EPR/ENDOR Study of the Decay of Trapped Radicals in Photopolymerized Butane-1,4-diol Diacrylate (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• EPR/ENDOR Study of the Decay of Trapped Radicals in Photopolymerized Butane-1,4-diol Diacrylate (Articolo in rivista) (literal)

Anno

• 1992-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1002/poc.610050108 (literal)

Alternative label

• Cesare Oliva, Elena Selli, Alessandro Ponti, Ignazio Renato Bellobono, Roberto Morelli (1992)
  EPR/ENDOR Study of the Decay of Trapped Radicals in Photopolymerized Butane-1,4-diol Diacrylate
  in Journal of physical organic chemistry (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Cesare Oliva, Elena Selli, Alessandro Ponti, Ignazio Renato Bellobono, Roberto Morelli (literal)

Pagina inizio

• 55 (literal)

Pagina fine

• 61 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 5 (literal)

Rivista

• Journal of physical organic chemistry (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Diparlimen/o di Chimica fì'sica ed Elellrochimica e Cenlro CNR, Universila di Mi/ano, via Golgi 19, 1-20133 Milan. ltaly (literal)

Titolo

• EPR/ENDOR Study of the Decay of Trapped Radicals in Photopolymerized Butane-1,4-diol Diacrylate (literal)

Abstract

• l.nng-livcd Impped rndlcals prodnced during Ihe pholopolymerizalion ' or bulane-I,4-diol diaCT}'1I1te (DODA) were studied b}' EPR aod ENOOR speclro 'coPY IInd tbcir Ihermul dCCll)' \"'us followed by EPR measuremeob al different Icrnpenilures (40-120 °(:) l'or killelic ~tud). The EPR signal ~howcd !he superimposition 01' Iwo dill'erenl poHems, Il Ihree-line nnd a single-line speclrum. BOlh EPR pllllcrns decayed following flrsl-ordcr kinelics in Ihe investigated lemperalure mnge. Aclh'alion parameters of the d~cay were ublained. rIle EPR pnllern werc nllribulcd III Ihe same radical species silllaled in l1uid and in eros -lillked regions Clf Ihe phOIOpol}meriLCd BODA. Radicals 01' Ihe lalter kind undergo eleclron spin exchange slrong enough lo wasll out the h)'perfine splilling. The single-lIne widlh is mainly determjDed by electron spin dipole-dipole inleractioos. Thl' ENDOR re~ponse is unI)' of Ihe malrix killd, t~'pic,,1 o\' radicals in a solid pllase. l'hl' preseol model WAS 9150 compured with receDI titeralure rep(lns. (literal)

Prodotto di

• Sistemi funzionali a nanoparticelle magnetiche (PM.P04.009.001) (Modulo)
• Institute of molecular science and technologies (ISTM) (Istituto)

Autore CNR

• ALESSANDRO PONTI (Persona)

Incoming links:

Prodotto

• Institute of molecular science and technologies (ISTM) (Istituto)
• Sistemi funzionali a nanoparticelle magnetiche (PM.P04.009.001) (Modulo)

Autore CNR di

• ALESSANDRO PONTI (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of physical organic chemistry (Rivista)