Surface chemistry of RuO2/IrO2/TiO2 mixed-oxide electrodes: SIMS study of the changes induced by electrochemical treatments (Articolo in rivista)

Type
Label
  • Surface chemistry of RuO2/IrO2/TiO2 mixed-oxide electrodes: SIMS study of the changes induced by electrochemical treatments (Articolo in rivista) (literal)
Anno
  • 2000-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1002/1097-023 (literal)
Alternative label
  • Barison S. ; De Battisti A.; Fabrizio M.; Daolio S.; Piccirillo C. (2000)
    Surface chemistry of RuO2/IrO2/TiO2 mixed-oxide electrodes: SIMS study of the changes induced by electrochemical treatments
    in RCM. Rapid communications in mass spectrometry
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Barison S. ; De Battisti A.; Fabrizio M.; Daolio S.; Piccirillo C. (literal)
Pagina inizio
  • 2165 (literal)
Pagina fine
  • 2169 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://onlinelibrary.wiley.com/doi/10.1002/1097-0231%2820001215%2914:23%3C2165::AID-RCM148%3E3.0.CO;2-H/abstract (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 14 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 23 (literal)
Note
  • ISI Web of Science (WOS) (literal)
  • Scopu (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • 1,3,4 : IPELP CNR, Corso Stati Uniti 4, 35127 Padova, Italy / 2,5 : Dipartimento di Chimica dell'Università, Via Borsari 46, 44100 Ferrara, Italy (literal)
Titolo
  • Surface chemistry of RuO2/IrO2/TiO2 mixed-oxide electrodes: SIMS study of the changes induced by electrochemical treatments (literal)
Abstract
  • The IrO2/RuO2/TiO2 ternary system is well known for its electrocatalytic activity towards oxygen- and chlorine-evolution reactions. Electrochemical processing induces noticeable chemical and morphological modifications on these electrodes, depending on the noble metal oxide content. In this work, cathodic/anodic polarization and the oxygen-evolution reaction were studied in order to evaluate the electrocatalytic activity at various noble metal oxide percentages. The best performing electrode (30 mol% noble metal oxides) was analyzed before and after electrochemical tests by means of secondary ion mass spectrometry (SIMS) in order to determine the chemical composition modification which occurred on the surface and in deeper regions of the mixed-oxide film. (literal)
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