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C70 adsorbed on Cu(111): metallic character and molecular orientation (Articolo in rivista)
- Type
- Label
- C70 adsorbed on Cu(111): metallic character and molecular orientation (Articolo in rivista) (literal)
- Anno
- 2002-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1063/1.1467346 (literal)
- Alternative label
A. Goldoni, C. Cepek, R. Larciprete, L. Sangaletti, S. Pagliara, L. Floreano, R. Gotter, A. Verdini, A. Morgante, Y. Luo, and M. Nyberg (2002)
C70 adsorbed on Cu(111): metallic character and molecular orientation
in The Journal of chemical physics; AIP, American institute of physics, Melville, NY (Stati Uniti d'America)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- A. Goldoni, C. Cepek, R. Larciprete, L. Sangaletti, S. Pagliara, L. Floreano, R. Gotter, A. Verdini, A. Morgante, Y. Luo, and M. Nyberg (literal)
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- [ 1 ] Sincrotrone Trieste SCpA, I-34012 Trieste, Italy
[ 2 ] INFM, Lab TASC, I-34012 Trieste, Italy
[ 3 ] ENEA, Div Fis Applicata, I-00044 Frascati, Italy
[ 4 ] Univ Cattolica Sacro Cuore, INFM, I-25121 Brescia, Italy
[ 5 ] Univ Cattolica Sacro Cuore, Dipartimento Matemat, I-25121 Brescia, Italy
[ 6 ] Univ Trieste, Dipartmento Fis, I-34127 Trieste, Italy
[ 7 ] Royal Inst Technol, SCFAB Theoret Chem, S-10691 Stockholm, Sweden
[ 8 ] Stockholm Univ, SCFAB Fysikum, S-10691 Stockholm, Sweden (literal)
- Titolo
- C70 adsorbed on Cu(111): metallic character and molecular orientation (literal)
- Abstract
- We investigated the interaction of C-70 with the Cu(111) surface using x-ray photoelectron spectroscopy and x-ray absorption spectroscopy. The data point to a net charge transfer from the Cu substrate to the C-70 molecules directly bonded to the Cu atoms, providing a metallic character for a single layer of C-70 (monolayer) adsorbed on this surface. A strong dependence of the x-ray absorption spectra from the light polarization is also observed. By comparing these experimental data with density-functional calculations of the contribution to the x-ray absorption spectral line shape of the five inequivalent carbon atoms in the C-70 cage, we observed that the molecules are mainly oriented with the C5V axis perpendicular to the Cu surface. (literal)
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