Tailored Formation of N-Doped Nanoarchitectures by Diffusion-Controlled on-Surface (Cyclo)-Dehydrogenation of Heteroaromatics (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Tailored Formation of N-Doped Nanoarchitectures by Diffusion-Controlled on-Surface (Cyclo)-Dehydrogenation of Heteroaromatics (Articolo in rivista) (literal)

Anno

• 2013-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1021/nn400690e (literal)

Alternative label

• Anna Lisa Pinardi +, Gonzalo Otero-Irurueta +, Irene Palacio +, Jose Ignacio Martinez +, Carlos Sanchez-Sanchez +, Marta Tello +, Celia Rogero ?, Albano Cossaro §, Alexei Preobrajenski , Berta Gómez-Lor +, Andrej Jancarik , Irena G. Stará , Ivo Starý , M. Francisca Lopez +, Javier Méndez +, and Jose Angel Martin-Gago +#* (2013)
  Tailored Formation of N-Doped Nanoarchitectures by Diffusion-Controlled on-Surface (Cyclo)-Dehydrogenation of Heteroaromatics
  in ACS nano (Online); ACS, American chemical society, Washington, DC (Stati Uniti d'America)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Anna Lisa Pinardi +, Gonzalo Otero-Irurueta +, Irene Palacio +, Jose Ignacio Martinez +, Carlos Sanchez-Sanchez +, Marta Tello +, Celia Rogero ?, Albano Cossaro §, Alexei Preobrajenski , Berta Gómez-Lor +, Andrej Jancarik , Irena G. Stará , Ivo Starý , M. Francisca Lopez +, Javier Méndez +, and Jose Angel Martin-Gago +#* (literal)

Pagina inizio

• 3676 (literal)

Pagina fine

• 3684 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://biblioproxy.cnr.it:2054/doi/abs/10.1021/nn400690e (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 7 (literal)

Rivista

• ACS nano (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 8 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 4 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• + Instituto de Ciencia de Materiales de Madrid ((ICMM), Consejo Superior de Investigaciones Científicas (CSIC), Sor Juana Inés de la Cruz 3, Cantoblanco, 28049 Madrid, Spain ? Centro de Física de Materiales (CSIC-UPV/EHU), Materials Physics Center (MPC), Donostia International Physics Center (DIPC), 20018, San Sebastian, Spain § CNR-IOM, Laboratorio TASC, Basovizza SS-14, Km 163.5, I-34149 Trieste, Italy MAX-IV Laboratory, Lund University, Box 118, 22100 Lund, Sweden Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Flemingovo nám. 2, 16610 Prague 6, Czech Republic # Centro de Astrobiología (CSIC-INTA), Carretera de Torrejón a Ajalvir, km 4, 28850 Torrejón de Ardoz, Madrid, Spain (literal)

Titolo

• Tailored Formation of N-Doped Nanoarchitectures by Diffusion-Controlled on-Surface (Cyclo)-Dehydrogenation of Heteroaromatics (literal)

Abstract

• Surface-assisted cyclodehydrogenation and dehydrogenative polymerization of polycyclic (hetero)aromatic hydrocarbons (PAH) are among the most important strategies for bottom-up assembly of new nanostructures from their molecular building blocks. Although diverse compounds have been formed in recent years using this methodology, a limited knowledge on the molecular machinery operating at the nanoscale has prevented a rational control of the reaction outcome. We show that the strength of the PAH-substrate interaction rules the competitive reaction pathways (cyclodehydrogenation versus dehydrogenative polymerization). By controlling the diffusion of N-heteroaromatic precursors, the on-surface dehydrogenation can lead to monomolecular triazafullerenes and diazahexabenzocoronenes (N-doped nanographene), to N-doped oligomeric or polymeric networks, or to carbonaceous monolayers. Governing the on-surface dehydrogenation process is a step forward toward the tailored fabrication of molecular 2D nanoarchitectures distinct from graphene and exhibiting new properties of fundamental and technological interest. (literal)

Editore

• ACS, American chemical society (Editore)

Prodotto di

• MD.P06.016.001 Proprieta' elettroniche e strutturali di sistemi a bassa dimensionalita' (MD.P06.016.003) (Modulo)

Autore CNR

• ALBANO COSSARO (Persona)

Insieme di parole chiave

• Keywords of "Tailored Formation of N-Doped Nanoarchitectures by Diffusion-Controlled on-Surface (Cyclo)-Dehydrogenation of Heteroaromatics" (Insieme di parole chiave)

Incoming links:

Autore CNR di

• ALBANO COSSARO (Persona)

Prodotto

• MD.P06.016.001 Proprieta' elettroniche e strutturali di sistemi a bassa dimensionalita' (MD.P06.016.003) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• ACS nano (Rivista)

Editore di

• ACS, American chemical society (Editore)

Insieme di parole chiave di

• Keywords of "Tailored Formation of N-Doped Nanoarchitectures by Diffusion-Controlled on-Surface (Cyclo)-Dehydrogenation of Heteroaromatics" (Insieme di parole chiave)