http://www.cnr.it/ontology/cnr/individuo/prodotto/ID227123
Bifunctional metallodendrimers based on AB5 derivatives of cyclotriphosphazene as core and P,N ligands as terminal functions (Articolo in rivista)
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- Label
- Bifunctional metallodendrimers based on AB5 derivatives of cyclotriphosphazene as core and P,N ligands as terminal functions (Articolo in rivista) (literal)
- Anno
- 2014-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.ica.2013.05.021 (literal)
- Alternative label
Tristany, Mar; Laurent, Regis; Dib, Hanna; Gonsalvi, Luca; Peruzzini, Maurizio; Majoral, Jean-Pierre; Caminade, Anne-Marie (2014)
Bifunctional metallodendrimers based on AB5 derivatives of cyclotriphosphazene as core and P,N ligands as terminal functions
in Inorganica Chimica Acta (Testo stamp.); Elsevier BV, Amsterdam (Paesi Bassi)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Tristany, Mar; Laurent, Regis; Dib, Hanna; Gonsalvi, Luca; Peruzzini, Maurizio; Majoral, Jean-Pierre; Caminade, Anne-Marie (literal)
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- Rivista
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France; Université de Toulouse, UPS, INPT, F-31077 Toulouse Cedex 4, France; Consiglio Nazionale delle Ricerche, Istituto di Chimica dei Composti Organometallici, (ICCOM-CNR) Via Madonna del Piano 10, 50019, Sesto Fiorentino, Italy. (literal)
- Titolo
- Bifunctional metallodendrimers based on AB5 derivatives of cyclotriphosphazene as core and P,N ligands as terminal functions (literal)
- Abstract
- The specific functionalization of hexachlorocyclotriphosphazene with one function different from the five others was used for the synthesis of bifunctional dendrimers having one protected amine linked to the core and either 5 phosphines or 10 phosphine imines (P,N ligands) as terminal groups. In the latter case, reaction with PdCl2(COD) affords the corresponding complexes of the P,N ligands. All compounds were characterized by multinuclear NMR, and particularly by 31P NMR, which proved to be a very precious tool for the characterization of sophisticated structures such as dendrimers. (literal)
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