Rotational spectrum of cyanoacetylene solvated with helium atoms (Articolo in rivista)

Type
Label
  • Rotational spectrum of cyanoacetylene solvated with helium atoms (Articolo in rivista) (literal)
Anno
  • 2006-01-01T00:00:00+01:00 (literal)
Alternative label
  • Topic, W; Jager, W; Blinov, N; Roy, PN; Botti, M; Moroni, S (2006)
    Rotational spectrum of cyanoacetylene solvated with helium atoms
    in Journal of chemical physics online
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Topic, W; Jager, W; Blinov, N; Roy, PN; Botti, M; Moroni, S (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 125 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada; CASPUR, I-00185 Rome, Italy; INFM, DEMOCRITOS, Natl Simulat Ctr, I-34014 Trieste, Italy; SISSA, I-34014 Trieste, Italy (literal)
Titolo
  • Rotational spectrum of cyanoacetylene solvated with helium atoms (literal)
Abstract
  • The high resolution microwave spectra of He-N-HCCCN clusters were studied in the size ranges of 1-18 and 25-31. In the absence of an accompanying infrared study, rotational excitation energies were computed by the reptation quantum Monte Carlo method and used to facilitate the search and assignment of R(0) transitions from N > 6, as well as R(1) transitions with N > 1. The assignments in the range of 25-31 are accurate to +/- 2 cluster size units, with an essentially certain relative ordering. The rotational transition frequencies decrease with N=1-6 and then show oscillatory behavior for larger cluster sizes, which is now recognized to be a manifestation of the onset and microscopic evolution of superfluidity. For cluster sizes beyond completion of the first solvation shell the rotational frequencies increase significantly above the large-droplet limit. This behavior, common to other linear molecules whose interaction with He features a strong nearly equatorial minimum, is analyzed using path integral Monte Carlo simulations. The He density in the incipient second solvation shell is shown to open a new channel for long permutation cycles, thus increasing the decoupling of the quantum solvent from the rotation of the dopant molecule. (c) 2006 Institute of Physics. (literal)
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