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Pressure and temperature dependence of the Fano resonance in the Raman spectrum of A(2)FeMoO(6) systems (A=Sr,Ca) (Articolo in rivista)
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- Pressure and temperature dependence of the Fano resonance in the Raman spectrum of A(2)FeMoO(6) systems (A=Sr,Ca) (Articolo in rivista) (literal)
- Anno
- 2007-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1103/PhysRevB.76.172405 (literal)
- Alternative label
Marrocchelli, D; Postorino, P; Di Castro, D; Arcangeletti, E; Dore, P; Guidi, MC; Ray, S; Sarma, DD (2007)
Pressure and temperature dependence of the Fano resonance in the Raman spectrum of A(2)FeMoO(6) systems (A=Sr,Ca)
in Physical review. B, Condensed matter and materials physics (Online)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Marrocchelli, D; Postorino, P; Di Castro, D; Arcangeletti, E; Dore, P; Guidi, MC; Ray, S; Sarma, DD (literal)
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- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Univ Roma La Sapienza, Coherentia CNR INFM, I-00185 Rome, Italy; Univ Roma La Sapienza, Dipartimento Fis, I-00185 Rome, Italy; Indian Inst Sci, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India; Indian Assoc Cultivat Sci, Dept Mat Sci, Calcutta 700032, India; Indian Assoc Cultivat Sci, Ctr Adv Mat, Calcutta 700032, India (literal)
- Titolo
- Pressure and temperature dependence of the Fano resonance in the Raman spectrum of A(2)FeMoO(6) systems (A=Sr,Ca) (literal)
- Abstract
- We report on Raman measurements carried out on Ca2FeMoO6 and Sr2FeMoO6 double perovskites as functions of pressure (0-15 GPa) and of temperature (298-370 K). The Raman spectrum of both the samples is characterized by a phonon peak at similar to 460 cm(-1) whose large asymmetric profile is ascribed to a Fano resonance. The careful data analysis provides in particular the Fano asymmetry parameter q which results to be nearly independent from pressure and temperature, thus suggesting a remarkable stability of both charge-carrier density and charge-lattice coupling. Finally, our data allow us to ascribe the conductivity transition previously observed around 2 GPa in Sr2FeMoO6 not to an intrinsic property but to the pressure-induced opening of intergrain percolation paths. (literal)
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