Syntheses of monooxo-technetium(V) and -rhenium(V) complexes of the (o-hydroxyphenyl)diphenylphosphine ligand (POH). Crystal structure of [TcOCl(PO)(2)] (Articolo in rivista)

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  • Syntheses of monooxo-technetium(V) and -rhenium(V) complexes of the (o-hydroxyphenyl)diphenylphosphine ligand (POH). Crystal structure of [TcOCl(PO)(2)] (Articolo in rivista) (literal)
Anno
  • 1996-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/0020-1693(95)04835-9 (literal)
Alternative label
  • Bolzati C.; Tisato F.; Refosco F.; Bandoli G (1996)
    Syntheses of monooxo-technetium(V) and -rhenium(V) complexes of the (o-hydroxyphenyl)diphenylphosphine ligand (POH). Crystal structure of [TcOCl(PO)(2)]
    in Inorganica Chimica Acta (Testo stamp.); ELSEVIER SCIENCE SA, PO BOX 564, 1001 LAUSANNE (Svizzera)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Bolzati C.; Tisato F.; Refosco F.; Bandoli G (literal)
Pagina inizio
  • 125 (literal)
Pagina fine
  • 127 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://www.sciencedirect.com/science/article/pii/0020169395048359 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 247 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
  • Scopu (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • 1-3 : ICTIMA, CNR, Corso Stati Uniti 4, 35020 Padua, Italy / 4 : Dipto. di Science Farmaceutiche, Università di Padova, via Marzolo 5, 35131 Padua, Italy (literal)
Titolo
  • Syntheses of monooxo-technetium(V) and -rhenium(V) complexes of the (o-hydroxyphenyl)diphenylphosphine ligand (POH). Crystal structure of [TcOCl(PO)(2)] (literal)
Abstract
  • Reduction-substitution reaction of pertechnetate with (o-hydroxyphenyl)diphenylphosphine (POH) at a strictly controlled metal/ligand ratio yields red-violet rhomboids of [TcOCl(PO)(2)] (1). The isostructural complex [ReOCl(PO)(2)] (2) is instead prepared by ligand-exchange reactions from the labile [ReOCl4](-) precursor. The structure of 1 consists of monomeric units in which the distorted octahedral coordination geometry around Tc involves the P,O donor atoms from the two bidentate ligands, the Cl and oxo atoms. Crystal data: orthorhombic, space group P2(1)2(1)2(1), a=10.183(9), b=14.028(9), c=21.40(1) Angstrom, V=3057(3) Angstrom(3), Z=4, D-calc=1.53 g cm(-3); structure solution and refinement based on 2207 reflections converged at R = 0.041. (literal)
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