Phosphanyl-amino complexes of nickel(II): Synthesis and structure (Articolo in rivista)

Type
Label
  • Phosphanyl-amino complexes of nickel(II): Synthesis and structure (Articolo in rivista) (literal)
Anno
  • 1998-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1002/(SICI)1099-0682(199811)1998:11<1689::AID-EJIC1689>3.0.CO;2-E (literal)
Alternative label
  • Crociani L.; Tisato F.; Refosco F.; Bandoli G.; Corain B. (1998)
    Phosphanyl-amino complexes of nickel(II): Synthesis and structure
    in European journal of inorganic chemistry (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Crociani L.; Tisato F.; Refosco F.; Bandoli G.; Corain B. (literal)
Pagina inizio
  • 1689 (literal)
Pagina fine
  • 1697 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://onlinelibrary.wiley.com/doi/10.1002/(SICI)1099-0682(199811)1998:11%3C1689::AID-EJIC1689%3E3.0.CO;2-E/abstract (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 11 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
  • Scopu (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • 1-3 Ist. Chim. Tecn. Materiali Avanzati, C. N. R., C. so Stati Uniti, 4, I-35020 Padova, Italy 4 Dipto. di Scienze Farmaceutiche, Università di Padova, Via Marzolo 5, I-35131 Padova, Italy 5 Inst. F. Org. Chemie und Biochemie, TU München, Lichtenbergstraße 4, D-85747 Garching, Germany 5 Dipto. Chim. Ingegneria Chim. M., Via Vetoio Coppito Due, I-67010 L'Aquila, Italy 5 Ctro. Stud. Sulla Stabilita R., CNR, Università di Padova, via Marzolo 1, I-35131 Padova, Italy (literal)
Titolo
  • Phosphanyl-amino complexes of nickel(II): Synthesis and structure (literal)
Abstract
  • New neutral pentacoordinate nickel(II) complexes of the type [NiCl2(PR3)(P?N)] [PR3 = PMe3, PMe2Ph, PMePh2; P?N = 2-(diphenylphosphanyl)aniline (P?NH2), N-methyl-2-(diphenylphosphanyl)aniline (P?NHMe), N,N-dimethyl-2-(diphenylphosphanyl)aniline (P?NMe2)], as well as cationic tetracoordinate nickel(II) complexes of the type [NiCl(PR3)(P?N)]+ have been synthesized and characterized both in the solid state and in solution. Interesting X-ray structural data have been collected for each class of compounds, which show, inter alia, that the pentacoordinate neutral complexes can be isolated in two different molecular forms, namely squarepyramidal or bipyramidal-trigonal. (literal)
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