SYNTHESIS AND CHARACTERIZATION OF CYCLOPENTYLINDIUM(III) COMPOUNDS (Articolo in rivista)

Type
Label
  • SYNTHESIS AND CHARACTERIZATION OF CYCLOPENTYLINDIUM(III) COMPOUNDS (Articolo in rivista) (literal)
Anno
  • 1993-01-01T00:00:00+01:00 (literal)
Alternative label
  • ROSSETTO G.; BRIANESE N.; CAMPORESE A.; PORCHIA M.; ZANELLA P. (1993)
    SYNTHESIS AND CHARACTERIZATION OF CYCLOPENTYLINDIUM(III) COMPOUNDS
    in Gazzetta chimica italiana
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • ROSSETTO G.; BRIANESE N.; CAMPORESE A.; PORCHIA M.; ZANELLA P. (literal)
Pagina inizio
  • 279 (literal)
Pagina fine
  • 282 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 123 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 4 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • 1-5 CNR,IST CHIM & TECNOL INORGAN & MAT AVANZATI,C SO STATI UNITI 4,I-35020 PADUA,ITALY (literal)
Titolo
  • SYNTHESIS AND CHARACTERIZATION OF CYCLOPENTYLINDIUM(III) COMPOUNDS (literal)
Abstract
  • A series of organoindium compounds containing the cyclopentyl ligand (cyclopentyl = C5H9) has been prepared and characterized by elemental analysis and spectroscopic means (H-1 and C-13 NMR, IR, mass spectroscopy). Reaction of (C5H9)MgCl with InCl3 in the 3:1 or 2:1 molar ratio gave In(C5H9)3 and In(C5H9)2Cl, respectively. The latter can be obtained also by ligand exchange between InCl3 and In(C5H9)3. In(C5H9)2Cl reacts easily with LiNEt2 and LiPyr (HPyr = pyrazole) giving In(C5H9)2NEt2 and In(C5H9)2Pyr, respectively. On the basis of mass spectroscopy In(C5H9)2Cl, the amide and the pyrazolide derivatives are dimers in the vapour phase (literal)
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