Experimental study on gallium activity in the liquid Ga-Bi-Sn alloys using the EMF method with zirconia solid electrolyte (Articolo in rivista)

Type
Label
  • Experimental study on gallium activity in the liquid Ga-Bi-Sn alloys using the EMF method with zirconia solid electrolyte (Articolo in rivista) (literal)
Anno
  • 2008-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.3139/146.101774 (literal)
Alternative label
  • I. Katayama; D. Zivkovic; R. Novakovic; H. Yamashita (2008)
    Experimental study on gallium activity in the liquid Ga-Bi-Sn alloys using the EMF method with zirconia solid electrolyte
    in International journal of materials research
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • I. Katayama; D. Zivkovic; R. Novakovic; H. Yamashita (literal)
Pagina inizio
  • 1330 (literal)
Pagina fine
  • 1335 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 99 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 12 (literal)
Note
  • Scopu (literal)
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Res. Inst. for Ubiquitous Energy Devices, Adv. Ind. Sci. & Technol., Ikeda, Osaka, Japan; Univ. of Belgrade, Technical Faculty, Bor, Serbia; CNR-IENI, Via de Marini, 6 16149 Genoa, Italy; Graduate School of Engg., Osaka University, Osaka, Japan (literal)
Titolo
  • Experimental study on gallium activity in the liquid Ga-Bi-Sn alloys using the EMF method with zirconia solid electrolyte (literal)
Abstract
  • The EMF of galvanic cells with zirconia solid electrolytes was measured to determine the activity of gallium in liquid Ga-Bi-Sn alloys in the temperature range of 1000-1250 K along three pseudo-binary lines of (BiySn1-y)-Ga where y = 0.25, 0.50 and 0.75. A mixture of Ga and Ga2O3 was used as a reference electrode. The activity curves of Ga show positive deviations from ideality in the whole composition range. The excess free energies of mixing for Ga-Bi-Sn alloys have been calculated using the general solution model in the same temperature range and along same pseudo-binary lines. The gallium activities obtained by the EMF method and calculated using the general solution model at 1100 K were compared with literature data. (literal)
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