http://www.cnr.it/ontology/cnr/individuo/prodotto/ID22121
Experimental study on gallium activity in the liquid Ga-Bi-Sn alloys using the EMF method with zirconia solid electrolyte (Articolo in rivista)
- Type
- Label
- Experimental study on gallium activity in the liquid Ga-Bi-Sn alloys using the EMF method with zirconia solid electrolyte (Articolo in rivista) (literal)
- Anno
- 2008-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.3139/146.101774 (literal)
- Alternative label
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- I. Katayama; D. Zivkovic; R. Novakovic; H. Yamashita (literal)
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- Rivista
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
- Note
- Scopu (literal)
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Res. Inst. for Ubiquitous Energy Devices, Adv. Ind. Sci. & Technol., Ikeda, Osaka, Japan;
Univ. of Belgrade, Technical Faculty, Bor, Serbia;
CNR-IENI, Via de Marini, 6 16149 Genoa, Italy;
Graduate School of Engg., Osaka University, Osaka, Japan (literal)
- Titolo
- Experimental study on gallium activity in the liquid Ga-Bi-Sn alloys using the EMF method with zirconia solid electrolyte (literal)
- Abstract
- The EMF of galvanic cells with zirconia solid electrolytes was measured to determine the activity of gallium in liquid Ga-Bi-Sn alloys in the temperature range of 1000-1250 K along three pseudo-binary lines of (BiySn1-y)-Ga where y = 0.25, 0.50 and 0.75. A mixture of Ga and Ga2O3 was used as a reference electrode. The activity curves of Ga show positive deviations from ideality in the whole composition range. The excess free energies of mixing for Ga-Bi-Sn alloys have been calculated using the general solution model in the same temperature range and along same pseudo-binary lines. The gallium activities obtained by the EMF method and calculated using the general solution model at 1100 K were compared with literature data. (literal)
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