http://www.cnr.it/ontology/cnr/individuo/prodotto/ID219860
Swelling behavior and thermal stability of poly(methylmethacrylate) crosslinked by the oxozirconium cluster Zr4O2(methacrylate)(12) (Articolo in rivista)
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- Label
- Swelling behavior and thermal stability of poly(methylmethacrylate) crosslinked by the oxozirconium cluster Zr4O2(methacrylate)(12) (Articolo in rivista) (literal)
- Anno
- 2001-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1002/aoc.161 (literal)
- Alternative label
Trimmel G., Gross S., Kickelbick G., Schubert U. (2001)
Swelling behavior and thermal stability of poly(methylmethacrylate) crosslinked by the oxozirconium cluster Zr4O2(methacrylate)(12)
in Applied organometallic chemistry
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- Trimmel G., Gross S., Kickelbick G., Schubert U. (literal)
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- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Vienna Tech Univ, Inst Organ Chem, A-1060 Vienna, Austria (literal)
- Titolo
- Swelling behavior and thermal stability of poly(methylmethacrylate) crosslinked by the oxozirconium cluster Zr4O2(methacrylate)(12) (literal)
- Abstract
- A new isomer of the oxozirconium cluster Zr4O2(methacrylate)(12) was obtained by reaction of zirconium butoxide with an excess of methacrylic acid, Contrary to the known isomer, the structure is centrosymmetric with a planar, rhombic Zr-4 core, Copolymerization with a 56-207-fold excess of methlylmethacrylate results in cluster-crosslinked poly(methylmethacrylate) that swells in ethyl acetate but does not dissolve. The solvent uptake during smelling decreases and the thermal stability improves with an increasing portion of the cluster. (literal)
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