http://www.cnr.it/ontology/cnr/individuo/prodotto/ID219855
Electrospray ionization in the study of sol-gel processes: the polycondensation of Ti(O-n-Bu)(4) in the presence of Si(OEt)(4) (Articolo in rivista)
- Type
- Label
- Electrospray ionization in the study of sol-gel processes: the polycondensation of Ti(O-n-Bu)(4) in the presence of Si(OEt)(4) (Articolo in rivista) (literal)
- Anno
- 2001-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1002/rcm.240 (literal)
- Alternative label
Cristoni S., Armelao L., Gross S., Tondello E., Traldi P. (2001)
Electrospray ionization in the study of sol-gel processes: the polycondensation of Ti(O-n-Bu)(4) in the presence of Si(OEt)(4)
in RCM. Rapid communications in mass spectrometry; John Wiley & Sons, Ltd., Chichester (Regno Unito), Chichester (Regno Unito)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Cristoni S., Armelao L., Gross S., Tondello E., Traldi P. (literal)
- Pagina inizio
- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- CNR, Ctr Studio Stabil Reattiv Composti Coordinaz, I-35100 Padua, Italy
Dipartimento Chim Inorgan Met Organ & Analit, I-35100 Padua, Italy
CNR, Ist Tecnol Biomed Avanzate, I-20010 Milan, Italy (literal)
- Titolo
- Electrospray ionization in the study of sol-gel processes: the polycondensation of Ti(O-n-Bu)(4) in the presence of Si(OEt)(4) (literal)
- Abstract
- The polycondensation of Ti(O-n-Bu)(4) in presence of Si(OEt)(4) (Et = C2H5, Bu = C4H9) has been studied by electrospray ionization of their mixtures in methanol. Series of oligomers due to Ti(oMe)(4) (Me = CH3) polycondensation have been detected and represent the most abundant species. This result can be explained by the ready alcoholysis of Ti(O-n-Bu)(4) and by its fast kinetics of oligomerization. However a series of Ti,Si-containing oligomers, with molecular weights in the range 400-1300 Da, has also been detected. Their structures have been characterized by isotopic cluster analysis and MS/MS experiments, proving that they originate by reaction of Ti-OH and Si-OEt moieties. (literal)
- Editore
- Prodotto di
- Autore CNR
- Insieme di parole chiave
Incoming links:
- Prodotto
- Autore CNR di
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi
- Editore di
- Insieme di parole chiave di