http://www.cnr.it/ontology/cnr/individuo/prodotto/ID219141

Modification of Molecular Spin Crossover in Ultrathin Films (Articolo in rivista)

Type

Label

Modification of Molecular Spin Crossover in Ultrathin Films (Articolo in rivista) (literal)

Anno

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

Alternative label

Pronschinske, A; Chen, YF; Lewis, GF; Shultz, DA; Calzolari, A; Nardelli, MB; Dougherty, DB (2013)
Modification of Molecular Spin Crossover in Ultrathin Films
in Nano letters (Print); ACS, American chemical society, Washington, DC (Stati Uniti d'America)
(literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

Pronschinske, A; Chen, YF; Lewis, GF; Shultz, DA; Calzolari, A; Nardelli, MB; Dougherty, DB (literal)

Pagina inizio

Pagina fine

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Rivista

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Note

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N Carolina State Univ, Dept Phys, Raleigh, NC 27695 USA N Carolina State Univ, Dept Chem, Raleigh, NC 27695 USA Inst Nanosci, CNR NANO, I-41125 Modena, Italy Univ N Texas, Dept Phys, Denton, TX 76203 USA Univ N Texas, Dept Chem, Denton, TX 76203 USA Oak Ridge Natl Lab, CSMD, Oak Ridge, TN 37831 USA (literal)

Titolo

Abstract

Scanning tunneling microscopy and local conductance mapping show spin-state coexistence in bilayer films of Fe[(H(2)Bpz(2))(2)bpy] on Au(111) that is independent of temperature between 131 and 300 K. This modification of bulk behavior is attributed in part to the unique packing constraints of the bilayer film that promote deviations from bulk behavior. The local density of states measured for different spin states shows that high-spin molecules have a smaller transport gap than low-spin molecules and are in agreement with density functional theory calculations. (literal)

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