Magnetic properties of quinoidal oligothiophenes: more than good candidates for ambipolar organic semiconductors (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Magnetic properties of quinoidal oligothiophenes: more than good candidates for ambipolar organic semiconductors (Articolo in rivista) (literal)

Anno

• 2006-01-01T00:00:00+01:00 (literal)

Alternative label

• Ortiz R.P., Casado J., Hernández V., López-Navarrete J.T., Ortí E., Viruela P.M., Milián B.; Hotta S., Zotti G., Zecchin S., Vercelli, B. (2006)
  Magnetic properties of quinoidal oligothiophenes: more than good candidates for ambipolar organic semiconductors
  in Advanced functional materials (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Ortiz R.P., Casado J., Hernández V., López-Navarrete J.T., Ortí E., Viruela P.M., Milián B.; Hotta S., Zotti G., Zecchin S., Vercelli, B. (literal)

Pagina inizio

• 531 (literal)

Pagina fine

• 536 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 16 (literal)

Rivista

• Advanced functional materials (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Istituto per L'Energetica e le Interfasi (literal)

Titolo

• Magnetic properties of quinoidal oligothiophenes: more than good candidates for ambipolar organic semiconductors (literal)

Abstract

• A series of quinoidal oligothiophenes have been investigated by means of solid-state Fourier-transform (FT)-Raman and electron spin resonance (ESR) spectroscopies complemented with density functional theory calculations. FT-Raman spectra recorded as a function of temperature show that, upon laser irradiation, the molecules undergo a reversible structural evolution from a quinoid-type pattern at low temperature to an aromatic-type pattern at high temperature. Moreover, ESR spectra show that a portion of these compounds exists in a biradical state at room temperature. These seemingly disconnected findings and others, such as conformational isomerism, are consistently explained by the consideration of biradical species associated with the presence of low-lying triplet electronic states. In addition to the well-established versatility of quinoidal oligothiophenes regarding ambipolar electrical actuation in field-effect transistors, the exhibition of dual electrical and magnetic behavior leads to the prospect of new materials that have tunable electrical, optical, and magnetic properties. (literal)

Prodotto di

• Institute of Condensed Matter Chemistry and Energy Technologies (ICMATE) (Istituto)
• Nanostrutture funzionali su superfici elettrodiche (ET.P06.011.002) (Modulo)

Autore CNR

• SANDRO ZECCHIN (Persona)
• GIANNI ZOTTI (Unità di personale interno)
• BARBARA VERCELLI (Unità di personale interno)

Incoming links:

Prodotto

• Institute of Condensed Matter Chemistry and Energy Technologies (ICMATE) (Istituto)
• Nanostrutture funzionali su superfici elettrodiche (ET.P06.011.002) (Modulo)

Autore CNR di

• BARBARA VERCELLI (Unità di personale interno)
• SANDRO ZECCHIN (Persona)
• GIANNI ZOTTI (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Advanced functional materials (Rivista)