Optical, electrochemical, magnetic, and conductive properties of new polyindolocarbazoles and polydiindolocarbazoles (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Optical, electrochemical, magnetic, and conductive properties of new polyindolocarbazoles and polydiindolocarbazoles (Articolo in rivista) (literal)

Anno

• 2006-01-01T00:00:00+01:00 (literal)

Alternative label

• Blouin N., Michaud A., Wakim S., Boudreault P.L.T., Leclerc M., Vercelli B., Zecchin S., Zotti G. (2006)
  Optical, electrochemical, magnetic, and conductive properties of new polyindolocarbazoles and polydiindolocarbazoles
  
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Blouin N., Michaud A., Wakim S., Boudreault P.L.T., Leclerc M., Vercelli B., Zecchin S., Zotti G. (literal)

Pagina inizio

• 166 (literal)

Pagina fine

• 174 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 207 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• CNR IENI (literal)

Titolo

• Optical, electrochemical, magnetic, and conductive properties of new polyindolocarbazoles and polydiindolocarbazoles (literal)

Abstract

• New polyindolocarbazoles (PIC) and polydiindolocarbazoles (PDIC) have been synthesized using Yamamoto polymerization reaction. These polymers have been investigated by cyclic voltammetry, UV-Vis-NIR spectroelectrochemistry, electrochemical quartz crystal microbalance, in situ electron spin resonance, and in situ conductivity techniques. Two redox oxidation processes, each involving one electron per repeat unit, produce radical cations (free or p-dimerized) and dications. Each one-electron redox process is generally split into two due to the stabilization of mixed-valence states. The oxidative charge is delocalized over the polyconjugated backbone with neutral-polaron conductivities in the range 0.002–0.04 S _ cm_1 and polaron-bipolaron conductivities in the range 0.04–0.5 S _ cm_1. Conductivities are higher when nitrogen atoms are involved in the conjugation pathway. (literal)

Prodotto di

• Nanostrutture funzionali su superfici elettrodiche (ET.P06.011.002) (Modulo)
• Institute of Condensed Matter Chemistry and Energy Technologies (ICMATE) (Istituto)

Autore CNR

• BARBARA VERCELLI (Unità di personale interno)
• GIANNI ZOTTI (Unità di personale interno)
• SANDRO ZECCHIN (Persona)

Incoming links:

Prodotto

• Institute of Condensed Matter Chemistry and Energy Technologies (ICMATE) (Istituto)
• Nanostrutture funzionali su superfici elettrodiche (ET.P06.011.002) (Modulo)

Autore CNR di

• BARBARA VERCELLI (Unità di personale interno)
• SANDRO ZECCHIN (Persona)
• GIANNI ZOTTI (Unità di personale interno)