Electrodes Coated by Passive Oxide Films with a Thickness Profile: Modeling and Measurement (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Electrodes Coated by Passive Oxide Films with a Thickness Profile: Modeling and Measurement (Articolo in rivista) (literal)

Anno

• 2008-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1149/1.2976214 (literal)

Alternative label

• S. Cattarin; N. Comisso; M. Musiani; B. Tribollet (2008)
  Electrodes Coated by Passive Oxide Films with a Thickness Profile: Modeling and Measurement
  in Journal of the Electrochemical Society
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• S. Cattarin; N. Comisso; M. Musiani; B. Tribollet (literal)

Pagina inizio

• C543 (literal)

Pagina fine

• C549 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://scitation.aip.org/getabs/servlet/GetabsServlet?prog=normal&id=JESOAN00015500001100C543000001&idtype=cvips&gifs=yes&ref=no (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 155 (literal)

Rivista

• Journal of the Electrochemical Society (Rivista)

Note

• Scopu (literal)
• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• 1-3 : Istituto per l’Energetica e le Interfasi-Consiglio Nazionale delle Ricerche, 35127 Padova, Italy 4 : Laboratoire Interfaces et Systèmes Electrochimiques, UPR15 du CNRS, Université Pierre et Marie Curie, 75252 Paris Cedex 05, France (literal)

Titolo

• Electrodes Coated by Passive Oxide Films with a Thickness Profile: Modeling and Measurement (literal)

Abstract

• The impedance of a rectangular electrode coated by a resistive film is calculated for the cases of linear and exponential thickness profiles along the electrode length. The local film capacity and local film resistance of each surface element are assumed to be inversely and directly proportional to local film thickness, respectively. Experimental model electrodes are prepared by anodizing niobium or tantalum rectangular sheets with a setup allowing the progressive extraction of the electrode from the electrolyte, at a constant rate, while the cell voltage is increased according to a suitable program. The impedance of the coated electrode, measured at a potential close to the lowest anodization potential, agrees well with theory. In particular, the plot of the ohmic resistance corrected phase angle vs frequency shows a minimum. The effect of experimental parameters such as thickness profile or solution concentration can be interpreted on the basis of the calculations. (literal)

Prodotto di

• Materiali e Processi per l'Elettrochimica dell'Idrogeno e l'Elettrocatalisi (ET.P06.011.001) (Modulo)
• Institute of Condensed Matter Chemistry and Energy Technologies (ICMATE) (Istituto)

Autore CNR

• SANDRO CATTARIN (Unità di personale interno)
• NICOLA COMISSO (Unità di personale interno)
• MARCO MUSIANI (Persona)

Insieme di parole chiave

• Keywords of "Electrodes Coated by Passive Oxide Films with a Thickness Profile: Modeling and Measurement" (Insieme di parole chiave)

Incoming links:

Autore CNR di

• NICOLA COMISSO (Unità di personale interno)
• MARCO MUSIANI (Persona)
• SANDRO CATTARIN (Unità di personale interno)

Prodotto

• Institute of Condensed Matter Chemistry and Energy Technologies (ICMATE) (Istituto)
• Materiali e Processi per l'Elettrochimica dell'Idrogeno e l'Elettrocatalisi (ET.P06.011.001) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of the Electrochemical Society (Rivista)

Insieme di parole chiave di

• Keywords of "Electrodes Coated by Passive Oxide Films with a Thickness Profile: Modeling and Measurement" (Insieme di parole chiave)