Low-defect neutral, cationic, and anionic conducting polymers from electrochemical polymerization of n-substituted bipyrroles. Synthesis, characterization, and EQCM analysis. (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Low-defect neutral, cationic, and anionic conducting polymers from electrochemical polymerization of n-substituted bipyrroles. Synthesis, characterization, and EQCM analysis. (Articolo in rivista) (literal)

Anno

• 2002-01-01T00:00:00+01:00 (literal)

Alternative label

• Zotti G., Zecchin S., Schiavon G., Berlin A., B. Vercelli (2002)
  Low-defect neutral, cationic, and anionic conducting polymers from electrochemical polymerization of n-substituted bipyrroles. Synthesis, characterization, and EQCM analysis.
  in Chemistry of materials
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Zotti G., Zecchin S., Schiavon G., Berlin A., B. Vercelli (literal)

Pagina inizio

• 3607 (literal)

Pagina fine

• 3614 (literal)

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• 14 (literal)

Rivista

• Chemistry of materials (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#descrizioneSinteticaDelProdotto

• Various 2,2’-bipyrroles N-substituted with alkyl, alkylsulfonate, or alkylammonium moieties have been anodically coupled to polymers. The polymers were characterized by cyclic voltammetry, UV-vis and FTIR spectroscopies, EQCM, and in situ conductivity. Coupling of dipyrroles instead of pyrroles minimizes the introduction of overoxidative defects into the polymer chain (from FTIR spectroscopy). The polymer of N-alkylammonium-Nhexyldipyrrole is soluble in acetonitrile. EQCM analysis of the oxidative doping process of the polymers in acetonitrile has shown that the alkyl- and alkylammonium-substituted polymers increase their mass with doping, whereas the mass decreases in the case of alkylsulfonate-substituted polymers provided with tetralkylammonium counterions. Electrochemical muscles built from the most representative polymers show marked deflections that follow the EQCM mass/charge changes. (literal)

Note

• ISI Web of Science (WOS) (literal)

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• Istituto CNR per l’ Energetica e le Interfasi, C.o Stati Uniti 4, 35127 Padova, Italy Istituto CNR di Scienze e Tecnologie Molecolari, via C.Golgi 19, 20133 Milano, Italy (literal)

Titolo

• Low-defect neutral, cationic, and anionic conducting polymers from electrochemical polymerization of n-substituted bipyrroles. Synthesis, characterization, and EQCM analysis. (literal)

Prodotto di

• Institute of Condensed Matter Chemistry and Energy Technologies (ICMATE) (Istituto)

Autore CNR

• SANDRO ZECCHIN (Persona)
• GILBERTO SCHIAVON (Persona)
• GIANNI ZOTTI (Unità di personale interno)
• BARBARA VERCELLI (Unità di personale interno)

Insieme di parole chiave

• Parole chiave di "Low-defect neutral, cationic, and anionic conducting polymers from electrochemical polymerization of n-substituted bipyrroles. Synthesis, characterization, and EQCM analysis." (Insieme di parole chiave)

Incoming links:

Prodotto

• Institute of Condensed Matter Chemistry and Energy Technologies (ICMATE) (Istituto)

Autore CNR di

• GILBERTO SCHIAVON (Persona)
• BARBARA VERCELLI (Unità di personale interno)
• SANDRO ZECCHIN (Persona)
• GIANNI ZOTTI (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Chemistry of materials (Rivista)

Insieme di parole chiave di

• Parole chiave di "Low-defect neutral, cationic, and anionic conducting polymers from electrochemical polymerization of n-substituted bipyrroles. Synthesis, characterization, and EQCM analysis." (Insieme di parole chiave)