Interplay between \"neutral\" and \"charge-transfer\"excimers rules the excited state decay in adenine-rich polynucleotides (Articolo in rivista)

Type
Label
  • Interplay between \"neutral\" and \"charge-transfer\"excimers rules the excited state decay in adenine-rich polynucleotides (Articolo in rivista) (literal)
Anno
  • 2011-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1002/anie.201104382 (literal)
Alternative label
  • Improta R, Barone V. (2011)
    Interplay between "neutral" and "charge-transfer"excimers rules the excited state decay in adenine-rich polynucleotides
    in Angewandte Chemie International Edition
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Improta R, Barone V. (literal)
Pagina inizio
  • 12016 (literal)
Pagina fine
  • 12019 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 50 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 4 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 50 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Istituto di Biostrutture Biommagini (IBB-CNR), Napoli (Italy) Scuola Normale Superiore, Piazza dei Cavalieri, 7 56126 Pisa (Italy) (literal)
Titolo
  • Interplay between \"neutral\" and \"charge-transfer\"excimers rules the excited state decay in adenine-rich polynucleotides (literal)
Abstract
  • The excited states of (dA)4 oligonucleotides (A=adenine), including the phosphoribose backbone, were studied in water at a fully quantum mechanical level, providing an atomistic description of the main decay paths and a comprehensive interpretation of the experimental data (see picture). After absorption to exciton states delocalized over multiple A bases, the behavior of the excited state is ruled by the interplay of a number of species responsible for different spectral features. (literal)
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