Direct synthesis of alpha-hydroxy acids through selective oxidation of diols mediated by homogeneous and heterogeneous TEMPO (Comunicazione a convegno)

Type

• Comunicazione a convegno (Classe)
• Prodotto della ricerca (Classe)

Label

• Direct synthesis of alpha-hydroxy acids through selective oxidation of diols mediated by homogeneous and heterogeneous TEMPO (Comunicazione a convegno) (literal)

Anno

• 2004-01-01T00:00:00+01:00 (literal)

Alternative label

• Maria Luisa Testa, Pamela Gancitano, Rosaria Ciriminna, Mario Pagliaro (2004)
  Direct synthesis of alpha-hydroxy acids through selective oxidation of diols mediated by homogeneous and heterogeneous TEMPO
  in ECSOC-8. 8th International Electronic Conference on Synthetic Organic Chemistry, WEB, 1-30 november 2004
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Maria Luisa Testa, Pamela Gancitano, Rosaria Ciriminna, Mario Pagliaro (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#altreInformazioni

• Contribute included in SECTION A: GENERAL ORGANIC SYNTHESIS (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://www.usc.es/congresos/ecsoc/8/conference.htm (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Istituto per lo Studio dei Materiali Nanostrutturati, CNR, Palermo (Italy) (literal)

Titolo

• Direct synthesis of alpha-hydroxy acids through selective oxidation of diols mediated by homogeneous and heterogeneous TEMPO (literal)

Abstract

• alpha-Hydroxy acids are pivotal components in a variety of compounds with important biological activity. Here we report an easy strategy which allows to synthesise a-hydroxy acids in a two-step oxidation process, involving first the cis-dihydroxylation of a terminal alkenes (catalyzed by ruthenium) followed by subsequent oxidation with TEMPO either dissolved in the homogeneous phase or entrapped in a sol-gel matrix. This work extends what we recently found concerning the synthesis of amino hydroxy acids by oxidation of the primary hydroxyls in aminodiols. (literal)

Prodotto di

• Nanomateriali multifunzionali per applicazioni chimiche avanzate (PM.P03.003.003) (Modulo)
• Istituto per lo studio dei materiali nanostrutturati (ISMN) (Istituto)

Autore CNR

• MARIO PAGLIARO (Unità di personale interno)
• ROSARIA CIRIMINNA (Unità di personale interno)
• MARIA LUISA TESTA (Persona)

Incoming links:

Autore CNR di

• MARIO PAGLIARO (Unità di personale interno)
• ROSARIA CIRIMINNA (Unità di personale interno)
• MARIA LUISA TESTA (Persona)

Prodotto

• Istituto per lo studio dei materiali nanostrutturati (ISMN) (Istituto)
• Nanomateriali multifunzionali per applicazioni chimiche avanzate (PM.P03.003.003) (Modulo)