Synthesis and Reactivity of Manganese Tricarbonyl Complexes of the Centropolyindanes 10-Methyltribenzotriquinacene and Fenestrindane (Articolo in rivista)

Type
Label
  • Synthesis and Reactivity of Manganese Tricarbonyl Complexes of the Centropolyindanes 10-Methyltribenzotriquinacene and Fenestrindane (Articolo in rivista) (literal)
Anno
  • 2000-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1021/om000114j (literal)
Alternative label
  • Dullaghan C, A., Carpenter G. B., Kuck D., Fusco C., Curci R., Sweigart D. A. (2000)
    Synthesis and Reactivity of Manganese Tricarbonyl Complexes of the Centropolyindanes 10-Methyltribenzotriquinacene and Fenestrindane
    in Organometallics
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Dullaghan C, A., Carpenter G. B., Kuck D., Fusco C., Curci R., Sweigart D. A. (literal)
Pagina inizio
  • 2233 (literal)
Pagina fine
  • 2236 (literal)
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  • 19 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 4 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Department of Chemistry, Brown University, Providence, Rhode Island 02912 Fakultät für Chemie, Universität Bielefeld, Universitätsstrasse 25, D-33615 Bielefeld, Germany CNR Centre MISO, Department of Chemistry, University of Bari, Via Amendola 173, Bari, Italy 70126 (literal)
Titolo
  • Synthesis and Reactivity of Manganese Tricarbonyl Complexes of the Centropolyindanes 10-Methyltribenzotriquinacene and Fenestrindane (literal)
Abstract
  • The cationic manganese tricarbonyl moiety is readily coordinated to an arene ring of the centropolyindanes 10-methyltribenzotriquinacene (MTBT) and fenestrindane (FET) to afford [(MTBT)Mn(CO)(3)](+) (1) and [(FET)Mn(CO)(3)](+) (2). An X-ray structure of 1 shows that the metal is coordinated to the convex face of the MTBT ligand. Both 1 and 2 are electrophilically activated and readily undergo regioselective and stereoselective addition reactions with mild nucleophiles. (literal)
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