http://www.cnr.it/ontology/cnr/individuo/prodotto/ID210431
Synthesis and Reactivity of Manganese Tricarbonyl Complexes of the Centropolyindanes 10-Methyltribenzotriquinacene and Fenestrindane (Articolo in rivista)
- Type
- Label
- Synthesis and Reactivity of Manganese Tricarbonyl Complexes of the Centropolyindanes 10-Methyltribenzotriquinacene and Fenestrindane (Articolo in rivista) (literal)
- Anno
- 2000-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1021/om000114j (literal)
- Alternative label
Dullaghan C, A., Carpenter G. B., Kuck D., Fusco C., Curci R., Sweigart D. A. (2000)
Synthesis and Reactivity of Manganese Tricarbonyl Complexes of the Centropolyindanes 10-Methyltribenzotriquinacene and Fenestrindane
in Organometallics
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Dullaghan C, A., Carpenter G. B., Kuck D., Fusco C., Curci R., Sweigart D. A. (literal)
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- Pagina fine
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- Rivista
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- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Department of Chemistry, Brown University, Providence, Rhode Island 02912
Fakultät für Chemie, Universität Bielefeld, Universitätsstrasse 25,
D-33615 Bielefeld, Germany
CNR Centre MISO, Department of Chemistry, University of Bari, Via Amendola 173,
Bari, Italy 70126 (literal)
- Titolo
- Synthesis and Reactivity of Manganese Tricarbonyl Complexes of the Centropolyindanes 10-Methyltribenzotriquinacene and Fenestrindane (literal)
- Abstract
- The cationic manganese tricarbonyl moiety is readily coordinated to an arene ring of the centropolyindanes 10-methyltribenzotriquinacene (MTBT) and fenestrindane (FET) to afford [(MTBT)Mn(CO)(3)](+) (1) and [(FET)Mn(CO)(3)](+) (2). An X-ray structure of 1 shows that the metal is coordinated to the convex face of the MTBT ligand. Both 1 and 2 are electrophilically activated and readily undergo regioselective and stereoselective addition reactions with mild nucleophiles. (literal)
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- Autore CNR
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