Transition Metal Complexes with the C1-Symmetric Diphosphines (R)-(R)-3-benzyl-2,4-bis(diphenylphosphino)pentane and (R)-(R)-3-benzyl(p-sulphonate)-2,4-bis(diphenylphosphino)pentane sodium salt. Applications to Enantioselective Catalysis in Different Phase-systems (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Transition Metal Complexes with the C1-Symmetric Diphosphines (R)-(R)-3-benzyl-2,4-bis(diphenylphosphino)pentane and (R)-(R)-3-benzyl(p-sulphonate)-2,4-bis(diphenylphosphino)pentane sodium salt. Applications to Enantioselective Catalysis in Different Phase-systems (Articolo in rivista) (literal)

Anno

• 2001-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/S0022-328X(00)00859-7 (literal)

Alternative label

• Bianchini, Claudio; Barbaro, Pierluigi; Scapacci, Giancarlo (2001)
  Transition Metal Complexes with the C1-Symmetric Diphosphines (R)-(R)-3-benzyl-2,4-bis(diphenylphosphino)pentane and (R)-(R)-3-benzyl(p-sulphonate)-2,4-bis(diphenylphosphino)pentane sodium salt. Applications to Enantioselective Catalysis in Different Phase-systems
  in Journal of organometallic chemistry (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Bianchini, Claudio; Barbaro, Pierluigi; Scapacci, Giancarlo (literal)

Pagina inizio

• 26 (literal)

Pagina fine

• 33 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 621 (literal)

Rivista

• Journal of organometallic chemistry (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Istituto per lo Studio della Stereochimica ed Energetica dei Composti di Coordinazione, ISSECC-CNR, Via J. Nardi 39, I-50132 Florence, Italy (literal)

Titolo

• Transition Metal Complexes with the C1-Symmetric Diphosphines (R)-(R)-3-benzyl-2,4-bis(diphenylphosphino)pentane and (R)-(R)-3-benzyl(p-sulphonate)-2,4-bis(diphenylphosphino)pentane sodium salt. Applications to Enantioselective Catalysis in Different Phase-systems (literal)

Abstract

• The C1-symmetric diphosphine (R)-(R)-3-benzyl-2,4-bis(diphenylphosphino)pentane [(R)-(R)-BDPBzP] has been employed, in combination with Ru(II), Rh(I), Ir(I) and Pd(II) ions, in a variety of homogeneous asymmetric reactions spanning from the hydrogenation of dimethyl itaconate, methyl 2-acetamidocinnamate, 2-methylquinoxaline, methyl pyruvate and dihydro-4,4- dimethyl-2,3-furandione, to the hydroboration of styrene, to the allylic alkylation of (rac)-(E)-3-acetoxy-1,3-diphenyl-1-propene with dimethyl malonate. The aqueous-biphase hydrogenation of dimethyl itaconate has been accomplished with Rh(I) and Ir(I) complexes containing the monosulphonated derivative (R)-(R)-3-benzyl(p-sulphonate)-2,4-bis(diphenylphosphino)pentane [(R)- (R)-BDPBzPSO3]. Irrespective of the phase variation system, the catalyst precursors generally feature good activity and good to modest enantioselectivity. (literal)

Prodotto di

• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)
• Sostenibilità in processi selettivi: catalizzatori, metodologie e approcci innovativi (PM.P03.002.001) (Modulo)

Autore CNR

• GIANCARLO SCAPACCI (Persona)
• CLAUDIO BIANCHINI (Persona)
• PIERLUIGI BARBARO (Unità di personale interno)

Incoming links:

Prodotto

• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)
• Sostenibilità in processi selettivi: catalizzatori, metodologie e approcci innovativi (PM.P03.002.001) (Modulo)

Autore CNR di

• PIERLUIGI BARBARO (Unità di personale interno)
• CLAUDIO BIANCHINI (Persona)
• GIANCARLO SCAPACCI (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of organometallic chemistry (Rivista)