Imaging photoelectron transmission through self-assembled monolayers: The work-function of alkanethiols coated gold (Articolo in rivista)

Type
Label
  • Imaging photoelectron transmission through self-assembled monolayers: The work-function of alkanethiols coated gold (Articolo in rivista) (literal)
Anno
  • 2007-01-01T00:00:00+01:00 (literal)
Alternative label
  • Fragouli, D; Kitsopoulos, TN; Chiodo, L; Della Sala, F; Cingolani, R; Ray, SG; Naaman, R (2007)
    Imaging photoelectron transmission through self-assembled monolayers: The work-function of alkanethiols coated gold
    in Langmuir
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Fragouli, D; Kitsopoulos, TN; Chiodo, L; Della Sala, F; Cingolani, R; Ray, SG; Naaman, R (literal)
Pagina inizio
  • 6156 (literal)
Pagina fine
  • 6162 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 23 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Univ Crete, FORTH, Inst Elect Struct & Laser, Iraklion 71110, Greece; Univ Crete, Dept Chem, Iraklion 71110, Greece; Ist Nazl Fis Nucl, CNR, Natl Nanotechnol Lab, I-73100 Lecce, Italy; Weizmann Inst Sci, Dept Chem Phys, IL-76100 Rehovot, Israel (literal)
Titolo
  • Imaging photoelectron transmission through self-assembled monolayers: The work-function of alkanethiols coated gold (literal)
Abstract
  • In this paper, we present a new approach for studying the electronic properties of self-assembled monolayers and their interaction with a conductive substrate, the low-energy photoelectron imaging spectroscopy (LEPIS). LEPIS relies on imaging of photoelectrons ejected from a conductive substrate and subsequently transmitted through organic monolayers. Using this method, we measure the relative work-function of alkanethiols of different length on gold substrate, and we are able to follow the changes occurring when the surface coverage is varied. We also computed the work-function of model alkanethiols using a plane-wave density functional theory approach, in order to demonstrate the correlation between changes in the work-function with the monolayer organization and density. (literal)
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