Speciation analysis of mercury in seawater from the Lagoon of Venice by on-line preconcentration HPLC-ICP-MS (Articolo in rivista)

Type
Label
  • Speciation analysis of mercury in seawater from the Lagoon of Venice by on-line preconcentration HPLC-ICP-MS (Articolo in rivista) (literal)
Anno
  • 2008-01-01T00:00:00+01:00 (literal)
Alternative label
  • Cairns W., Ranaldo M., Hennebelle R., Turetta C., Capodaglio G., Ferrari C., Cescon P., Barbante C. (2008)
    Speciation analysis of mercury in seawater from the Lagoon of Venice by on-line preconcentration HPLC-ICP-MS
    in Analytica chimica acta (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Cairns W., Ranaldo M., Hennebelle R., Turetta C., Capodaglio G., Ferrari C., Cescon P., Barbante C. (literal)
Pagina inizio
  • 62 (literal)
Pagina fine
  • 69 (literal)
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  • 622 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Institute for the Dynamics of Environmental Processes-CNR, Calle Larga Santa Marta 2137, 30123 Venice, Italy Department of Environmental Sciences, University Ca' Foscari, Calle Larga Santa Marta 2137, 30123 Venezia, Italy Laboratoire de Glaciologie et de G´eophysique de l'Environnement, 54 rue Moli`ere, BP 96, 38402 St Martin d'H`eres, France (literal)
Titolo
  • Speciation analysis of mercury in seawater from the Lagoon of Venice by on-line preconcentration HPLC-ICP-MS (literal)
Abstract
  • A method based on the coupling of HPLC with ICP-MS with an on-line pre-concentration micro-column has been developed for the analysis of inorganic and methyl mercury in the dissolved phase of natural waters. This method allows the rapid pre-concentration and matrix removal of interferences in complex matrices such as seawater with minimal sampling handling. Detection limits of 0.07 ngL-1 for inorganic mercury and 0.02 ngL-1 for methyl mercury have been achieved allowing the determination of inorganic mercury and methyl mercury in filtered seawater from the Venice lagoon. Good accuracy and reproducibility was demonstrated by the repeat a-..,lalysis of the certified reference material BCR-S79 coastal seawater. The developed HPLC separation was shown to be also suitable for the determination of methyl mercury in extracts of the particulate phase. (c) 2008 Elsevier B.V. All rights reserved. (literal)
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