Formic Acid Dehydrogenation Catalysed by Ruthenium Complexes bearing the Tripodal Ligands Triphos and NP3 (Articolo in rivista)

Type
Label
  • Formic Acid Dehydrogenation Catalysed by Ruthenium Complexes bearing the Tripodal Ligands Triphos and NP3 (Articolo in rivista) (literal)
Anno
  • 2013-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1039/C2DT32043F (literal)
Alternative label
  • Mellone, Irene; Peruzzini, Maurizio; Rosi, Luca; Mellman, Doerthe; Junge, Henrik; Beller, Matthias; Gonsalvi, Luca (2013)
    Formic Acid Dehydrogenation Catalysed by Ruthenium Complexes bearing the Tripodal Ligands Triphos and NP3
    in Dalton transactions (2003. Online); Royal Society of Chemistry, Cambridge (Regno Unito)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Mellone, Irene; Peruzzini, Maurizio; Rosi, Luca; Mellman, Doerthe; Junge, Henrik; Beller, Matthias; Gonsalvi, Luca (literal)
Pagina inizio
  • 2495 (literal)
Pagina fine
  • 2501 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 42 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Consiglio Nazionale delle Ricerche, Istituto di Chimica dei Composti Organometallici (CNR-ICCOM), Via Madonna del Piano 10, 50019 Sesto Fiorentino, Italy; Dipartimento di Chimica, Università degli Studi di Firenze, Via della Lastruccia, 3-13, 50019 Sesto Fiorentino, Italy; Leibniz-Institute for Catalysis (LIKAT) at the University of Rostock, Albert-Einstein Strasse 29a, 18059 Rostock, Germany (literal)
Titolo
  • Formic Acid Dehydrogenation Catalysed by Ruthenium Complexes bearing the Tripodal Ligands Triphos and NP3 (literal)
Abstract
  • The selective formic acid dehydrogenation to a mixture of CO2 and H2 was achieved with moderate to good productivities in the presence of homogeneous Ru catalysts bearing the polydentate tripodal ligands 1,1,1-tris-(diphenylphosphinomethyl)ethane (triphos) and tris-[2-(diphenylphosphino)ethyl]amine (NP3), either made in situ from suitable Ru(III) precursors or as molecular complexes. Preliminary mechanistic studies highlighting subtle differences due to ligand effects in the corresponding systems under study are also presented. (literal)
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