The Rabe amination after a century: direct addition of N-heterocycles to carbonyl compounds (Articolo in rivista)

Type
Label
  • The Rabe amination after a century: direct addition of N-heterocycles to carbonyl compounds (Articolo in rivista) (literal)
Anno
  • 2012-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1039/ c2ob25595b (literal)
Alternative label
  • D. M. Scarpino Schietroma, M. R. Monaco, V. Bucalossi, P. E. Walter, P. Gentili, M. Bella (2012)
    The Rabe amination after a century: direct addition of N-heterocycles to carbonyl compounds
    in Organic & biomolecular chemistry; The Royal Society of Chemistry, Cambridge (Regno Unito)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • D. M. Scarpino Schietroma, M. R. Monaco, V. Bucalossi, P. E. Walter, P. Gentili, M. Bella (literal)
Pagina inizio
  • 4692 (literal)
Pagina fine
  • 4695 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 10 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 4 (literal)
Note
  • ISI Web of Science (WOS) (literal)
  • Scopus (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Dipartimento di Chimica e IMC-CNR - Sezione Meccanismi di Rezione \"Sapienza\" Universit√† di Roma, P.le Aldo Moro 5, 00185 Roma, Italy (literal)
Titolo
  • The Rabe amination after a century: direct addition of N-heterocycles to carbonyl compounds (literal)
Abstract
  • A catalytic version of the Rabe electrophilic amination is presented. This kind of reaction was originally employed in 1918 in a key step for the conversion of quinotoxine to quinine. Ketones and ?-substituted aldehydes give the corresponding ?-aminated carbonyl compounds in moderate yield. ?,?- Unsubstituted aldehydes give rise to amino ketones via a novel rearrangement. (literal)
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