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Hydrothermal Synthesis of SrTiO3 Mesocrystals: Single Crystal to Mesocrystal Transformation Induced by Topochemical Reactions (Articolo in rivista)
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- Hydrothermal Synthesis of SrTiO3 Mesocrystals: Single Crystal to Mesocrystal Transformation Induced by Topochemical Reactions (Articolo in rivista) (literal)
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- 2012-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1021/cg300614f (literal)
- Alternative label
Kalyani V.; Vasile B.S.; Ianculescu A.; Buscaglia M.T.; Buscaglia V.; Nanni P. (2012)
Hydrothermal Synthesis of SrTiO3 Mesocrystals: Single Crystal to Mesocrystal Transformation Induced by Topochemical Reactions
in Crystal growth & design (Online); American Chemical Society, Washington (Stati Uniti d'America)
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- Kalyani V.; Vasile B.S.; Ianculescu A.; Buscaglia M.T.; Buscaglia V.; Nanni P. (literal)
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- 1,6 : Department of Process and Chemical Engineering, University of Genoa, Fiera Del Mare, P.le Kennedy, I-16129 Genoa, Italy /
1,4,5,6 : Institute for Energetics and Interphases, National Research Council, Via De Marini 6, I-16149 Genoa, Italy /
2,3 : Department of Science and Engineering of Oxide Materials, Polytechnics University of Bucharest, 1-7 Gh. Polizu, 011061 Bucharest, Romania (literal)
- Titolo
- Hydrothermal Synthesis of SrTiO3 Mesocrystals: Single Crystal to Mesocrystal Transformation Induced by Topochemical Reactions (literal)
- Abstract
- The mechanisms driving the mutual crystallographic alignment of nanocrystals in mesocrystals are various and not yet fully understood. As discussed in this paper, formation of mesocrystals can result from a topochemical reaction between single crystal particles or templates suspended in a liquid phase and ionic/molecular species in solution. In such a case, the initial particle morphology is retained in the final mesocrystal. If the transformation is not topotactic, the final product will maintain no memory of the precursor morphology. The magnitude of the lattice mismatch as well as the defective state of the precursor surface probably determine the degree of mutual crystallographic alignment of the nanocrystals which nucleate and grow on the substrate. Although identified by studying the hydrothermal crystallization of SrTiO3 from different single crystal titania precursors, this mechanism is very general and applicable to a variety of compounds and experimental situations, including solvothermal and molten salt syntheses. (literal)
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