http://www.cnr.it/ontology/cnr/individuo/prodotto/ID19864
Colloidal PbTe-Au nanocrystal heterostructures (Articolo in rivista)
- Type
- Label
- Colloidal PbTe-Au nanocrystal heterostructures (Articolo in rivista) (literal)
- Anno
- 2010-01-01T00:00:00+01:00 (literal)
- Alternative label
Franchini I.R., Bertoni G., Falqui A., Giannini C., Wang Wang L., Manna L. (2010)
Colloidal PbTe-Au nanocrystal heterostructures
in Journal of materials chemistry (Print)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Franchini I.R., Bertoni G., Falqui A., Giannini C., Wang Wang L., Manna L. (literal)
- Pagina inizio
- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Fondazione Istituto Italiano di Tecnologia, Genova
National Nanotechnology Laboratory of CNR-INFM, Lecce
CNR-Istituto di Cristallografia, Sede di Bari
Computational Research Division, Lawrence Berkeley National Laboratory, Berkeley, California, USA (literal)
- Titolo
- Colloidal PbTe-Au nanocrystal heterostructures (literal)
- Abstract
- Colloidal PbTe nanocrystals are reacted with AuCl3 in the presence of dodecylamine and
tetraoctylammonium bromide in a toluene solution. At room temperature, only homogenous
nucleation of isolated Au nanocrystals in solution is observed. At higher temperatures (i.e. 60 ?C or
higher) the gold ions/atoms are able to diffuse through the PbTe nanocrystals and to form one or more
metallic gold regions inside them, while most of the remaining volume of each nanocrystal becomes
amorphous. Longer reaction times lead to the growth of a single balloon-shaped Au domain attached
via its apex to the surface of each nanocrystal. The structural and compositional quantification of the
starting PbTe nanocrystals and of the various reaction products is often complicated by several reactive
processes occurring during in situ analysis by electron microscopy. Evidences of the formation of
a metastable Au3Te compound are presented. (literal)
- Prodotto di
- Autore CNR
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