http://www.cnr.it/ontology/cnr/individuo/prodotto/ID19833
Fluorescent Asymmetrically Cobalt-Tipped CdSe@CdS Core@Shell Nanorod Heterostructures Exhibiting Room-Temperature Ferromagnetic Behavior (Articolo in rivista)
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- Fluorescent Asymmetrically Cobalt-Tipped CdSe@CdS Core@Shell Nanorod Heterostructures Exhibiting Room-Temperature Ferromagnetic Behavior (Articolo in rivista) (literal)
- Anno
- 2009-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1021/ja904493c (literal)
- Alternative label
Deka S., Falqui A., Bertoni G., Sangregorio C., Poneti G., Morello G., De Giorgi M., Giannini C., Cingolani R., Manna L., Cozzoli P.D. (2009)
Fluorescent Asymmetrically Cobalt-Tipped CdSe@CdS Core@Shell Nanorod Heterostructures Exhibiting Room-Temperature Ferromagnetic Behavior
in Journal of the American Chemical Society (Print); American Chemical Society, Washington (Stati Uniti d'America)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Deka S., Falqui A., Bertoni G., Sangregorio C., Poneti G., Morello G., De Giorgi M., Giannini C., Cingolani R., Manna L., Cozzoli P.D. (literal)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- 1 ] CNR INFM, Natl Nanotechnol Lab, Unita Ric IIT, Distretto Tecnol ISUFI, I-73100 Lecce, Italy
2 ] Univ Salento, Scuola Super ISUFI, Distretto Tecnol ISUFI, I-73100 Lecce, Italy
3 ] IIT, Fdn Ist Italiano Tecnol, I-16163 Genoa, Italy
4 ] Univ Florence, UdR INSTM, I-50019 Sesto Fiorentino, Italy
5 ] Univ Florence, Dipartimento Chim, I-50019 Sesto Fiorentino, Italy
6 ] CNR, Ist Cristallog, I-70126 Bari, Italy (literal)
- Titolo
- Fluorescent Asymmetrically Cobalt-Tipped CdSe@CdS Core@Shell Nanorod Heterostructures Exhibiting Room-Temperature Ferromagnetic Behavior (literal)
- Abstract
- A colloidal two-step seeded-growth approach has been devised to selectively synthesize three-component magnetic/semiconductor hybrid nanocrystals (HNCs) with a matchstick-like profile and tunable geometric parameters. The newly developed heterostructures individually comprise a single metallic Co head connected to either apexes of one rod-shaped section made of a CdSe core eccentrically embedded in a CdS shell. The specific topological arrangement realized arises from the peculiar anisotropic reactivity of the noncentrosymmetric CdSe@CdS core@shell nanorods that have been used as substrates to seed heterogeneous nucleation of Cc in a surfactant-free environment from an organometallic precursor. The HNCs retain appreciable fluorescent emission in spite of photoexcited charge transfer from the semiconductor to the metal domain and exhibit unusual ferromagnetic-like behavior at room temperature. (literal)
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