Exchange-Coupled Bimagnetic Cobalt/Iron Oxide Branched Nanocrystal Heterostructures (Articolo in rivista)

Type
Label
  • Exchange-Coupled Bimagnetic Cobalt/Iron Oxide Branched Nanocrystal Heterostructures (Articolo in rivista) (literal)
Anno
  • 2009-01-01T00:00:00+01:00 (literal)
Alternative label
  • Casavola M., Falqui A., García M.A., García-Hernández M., Giannini C., Cingolani R., Cozzoli P.D. (2009)
    Exchange-Coupled Bimagnetic Cobalt/Iron Oxide Branched Nanocrystal Heterostructures
    in Nano letters (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Casavola M., Falqui A., García M.A., García-Hernández M., Giannini C., Cingolani R., Cozzoli P.D. (literal)
Pagina inizio
  • 366 (literal)
Pagina fine
  • 376 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 9 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • 1. Univ Salento, Scuola Super ISUFI, Distretto Tecnol ISUFI, I-73100 Lecce, Italy 2. INFM, CNR, Natl Nanotechnol Lab, Unita Ric IIT, I-73100 Lecce, Italy 3. IIT, I-16163 Genoa, Italy 4. Univ Complutense, Dept Mat Phys, E-28024 Madrid, Spain 5. CSIC, Inst Ceram & Vidrio, E-28049 Madrid, Spain 6. CSIC, Inst Ciencia Mat Madrid, E-28049 Madrid, Spain 7. CNR, Inst Cristallog, I-70126 Bari, Italy (literal)
Titolo
  • Exchange-Coupled Bimagnetic Cobalt/Iron Oxide Branched Nanocrystal Heterostructures (literal)
Abstract
  • A colloidal seeded-growth strategy, relying on time-programmed delivery of selected stabilizing surfactants, has been developed to synthesize bimagnetic hybrid nanocrystals (HNCs) that consist of a single-crystal tetrapod-shaped skeleton of ferrimagnetic (FiM) iron oxide functionalized with multiple polycrystalline spherical domains of ferromagnetic (FM) Co. Due to the direct bonding interfaces formed between the two materials at the relevant junction regions, the HNCs exhibit FiM-FM exchange coupling, which transcribes into a rich scenario of significantly modified properties (not otherwise achievable with any of the single components or with their physical mixtures), including higher saturation magnetization and coercitivity values, exchange biasing, and enhanced thermal stability due to induced extra anisotropy. The availability of these new types of HNCs suggests that development of appropriate synthetic tools for arranging distinct material domains in predetermined spatial arrangements could lead to a more rational design of nanoheterostructures potentially exploitable as active elements in future generations of magnetic recording devices. (literal)
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