http://www.cnr.it/ontology/cnr/individuo/prodotto/ID196471
Fullerene C60 Trichloromethylation Through CCl4 Plasmalysis or Sonolysis (Articolo in rivista)
- Type
- Label
- Fullerene C60 Trichloromethylation Through CCl4 Plasmalysis or Sonolysis (Articolo in rivista) (literal)
- Anno
- 2013-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1007/s11090-012-9417-5 (literal)
- Alternative label
F.Cataldo, O. Ursini, P. Ragni (2013)
Fullerene C60 Trichloromethylation Through CCl4 Plasmalysis or Sonolysis
in Plasma chemistry and plasma processing (Online); Kluwer, Dordrecht (Paesi Bassi)
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- F.Cataldo, O. Ursini, P. Ragni (literal)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
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- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- -Università di Tor Vergata, Department of Chemistry, Via della Ricerca Scientifica, 00133 Rome, Italy.
-Institute of Chemical Methodologies, CNR, Via Salaria Km. 29,300, 00016 Monterotondo Stazione, Rome, Italy (literal)
- Titolo
- Fullerene C60 Trichloromethylation Through CCl4 Plasmalysis or Sonolysis (literal)
- Abstract
- The trichloromethylation of C60 fullerene was achieved either under plasmalysis conditions, i.e. by arcing a solution of C60 in CCl4 between two graphite electrodes, or by sonolysis of C60 in CCl4. The resulting products were studied by UV-VIS and FT-IRs pectroscopy as well as by thermogravimetric analysis in comparison to the trichloromethyl adducts formed by radiolysis or photolysis of C60 in CCl4.
A reference study on the plasmalysis of pure CCl4 has revealed the formation of carbon soot and hexachlorobenzene.
The formation of the latter compound was suppressed when C60 was present in CCl4. (literal)
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