New palladium catalysts on polyketone prepared through different smart methodologies and their use in the hydrogenation of cinnamaldehyde (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• New palladium catalysts on polyketone prepared through different smart methodologies and their use in the hydrogenation of cinnamaldehyde (Articolo in rivista) (literal)

Anno

• 2012-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.apcata.2012.09.003 (literal)

Alternative label

• Anna Maria Raspolli Galletti, Luigi Toniolo, Claudia Antonetti, Claudio Evangelisti, Claudia Forte (2012)
  New palladium catalysts on polyketone prepared through different smart methodologies and their use in the hydrogenation of cinnamaldehyde
  in Applied catalysis. A, General (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Anna Maria Raspolli Galletti, Luigi Toniolo, Claudia Antonetti, Claudio Evangelisti, Claudia Forte (literal)

Pagina inizio

• 49 (literal)

Pagina fine

• 59 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://dx.doi.org/10.1016/j.apcata.2012.09.003 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 447-448 (literal)

Rivista

• Applied catalysis. A, General (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 11 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Department of Chemistry and Industrial Chemistry, University of Pisa, Via Risorgimento 36, 56126 Pisa, Italy Department of Molecular Sciences and Nanosystems, University Ca' Foscari of Venice, Dorsoduro 2137, 30123 Venice, Italy ICCOM CNR, Via G. Moruzzi 1, 56124 Pisa, Italy CNR ISTM, Via Fantoli 16, 20138 Milano, Italy (literal)

Titolo

• New palladium catalysts on polyketone prepared through different smart methodologies and their use in the hydrogenation of cinnamaldehyde (literal)

Abstract

• For the first time, polyketone (poly-3-oxotrimethylene, PK) has been employed as support for Pd nanoparticles. Three different approaches have been adopted: (i) reduction of Pd(OAc)2 in EtOH under microwave irradiation, (ii) hydrothermal reduction of the same precursor in EtOH or n-BuOH employing traditional heating and (iii) vaporization of Pd metal through metal vapour synthesis. These supported systems have been characterized by solid state NMR, TEM, ICP, XPS, BET and tested in the selective hydrogenation of cinnamaldehyde (CAL) to hydrocinnamaldehyde (HCAL) as probe reaction. Their catalytic performances have been compared in relation to their preparation procedure and morphology. It is remarkable that these catalysts do not show significant leaching even after several catalytic recycles, thus indicating their high stability and recyclability, ascribed to a stabilizing capacity of this particular polymeric support. (literal)

Prodotto di

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Catalizzatori per la produzione chemo-, regio- e stereoselettiva di fine chemicals (PM.P03.002.002) (Modulo)

Autore CNR

• CLAUDIO EVANGELISTI (Persona)
• CLAUDIA FORTE (Persona)

Incoming links:

Prodotto

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Catalizzatori per la produzione chemo-, regio- e stereoselettiva di fine chemicals (PM.P03.002.002) (Modulo)

Autore CNR di

• CLAUDIA FORTE (Persona)
• CLAUDIO EVANGELISTI (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Applied catalysis. A, General (Rivista)