http://www.cnr.it/ontology/cnr/individuo/prodotto/ID195559

H2 Production by Renewables Photoreforming on Pt-Au/TiO2 Catalysts Activated by Reduction (Articolo in rivista)

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H2 Production by Renewables Photoreforming on Pt-Au/TiO2 Catalysts Activated by Reduction (Articolo in rivista) (literal)

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Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

Alternative label

Alessandro Gallo , Tiziano Montini, Marcello Marelli, Alessandro Minguzzi, Valentina Gombac, Rinaldo Psaro, Paolo Fornasiero, Vladimiro Dal Santo (2012)
H2 Production by Renewables Photoreforming on Pt-Au/TiO2 Catalysts Activated by Reduction
in ChemSusChem (Weinh., Internet); WILEY-V C H VERLAG GMBH,, D-69451 WEINHEIM, (Germania)
(literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

Alessandro Gallo , Tiziano Montini, Marcello Marelli, Alessandro Minguzzi, Valentina Gombac, Rinaldo Psaro, Paolo Fornasiero, Vladimiro Dal Santo (literal)

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http://onlinelibrary.wiley.com/doi/10.1002/cssc.201200085/abstract;jsessionid=2D9B30BDE8A1B1103ACFB4EB7AE86333.d03t03 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

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Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

ICCOM-CNR and INSTM Università? degli Studi di Trieste, Via L. Giorgieri 1, 34127 Trieste (Italy) CNR - Istituto di Scienze e Tecnologie Molecolari, Via G. Fantoli, 16/15, 20138 Milano (Italy) Dipartimento di Chimica Fisica ed Elettrochimica Universit?à degli Studi di Milano, Via C. Golgi 19, 20133 Milano (Italy) CNR - Istituto di Scienze e Tecnologie Molecolari Via C. Golgi, 19, 20133 Milano (Italy) (literal)

Titolo

H2 Production by Renewables Photoreforming on Pt-Au/TiO2 Catalysts Activated by Reduction (literal)

Abstract

Bimetallic PtAu nanoparticles supported on reduced anatase nanocrystals represent a new class of promising photocatalysts with high activity in hydrogen production by photoreforming of aqueous solution of renewable feedstock, such as ethanol and glycerol. The catalysts are easily obtained by metal impregnation of commercial TiO2, followed by a reductive treatment. Remarkably, deeper catalyst pre-reduction results in enhanced photoactivity. When ethanol is used as sacrificial agent, under both UV-A or simulated sunlight irradiation, H2 is the most abundant product in the gas stream whereas, in the case of glycerol, significant amounts of CO2 have also been detected, indicating a more efficient oxidation of the organic sacrificial agent. The presence of bimetallic PtAu nanoparticles and of Ti3+ sites/O2- vacancies in the bulk structure of titania are two key parameters to maximize light absorption and feedstock activation, finally resulting in good photocatalytic performances. (literal)

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