Synthesis, characterization, CO2 uptake and catalytic properties of a chiral Co(II)-MOF containing a thiazolidine-based linker (Abstract/Poster in convegno)

Type
Label
  • Synthesis, characterization, CO2 uptake and catalytic properties of a chiral Co(II)-MOF containing a thiazolidine-based linker (Abstract/Poster in convegno) (literal)
Anno
  • 2012-01-01T00:00:00+01:00 (literal)
Alternative label
  • Rossin, Andrea; Giambastiani, Giuliano; Peruzzini, Maurizio; Tuci, Giulia; Bordiga, Silvia; Lamberti, Carlo (2012)
    Synthesis, characterization, CO2 uptake and catalytic properties of a chiral Co(II)-MOF containing a thiazolidine-based linker
    in 3rd International Conference on Metal-Organic Frameworks and Open Framework Compounds (MOF2012), Edinburgh (Scotland, United Kingdom), 16-19 settembre 2012
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Rossin, Andrea; Giambastiani, Giuliano; Peruzzini, Maurizio; Tuci, Giulia; Bordiga, Silvia; Lamberti, Carlo (literal)
Note
  • Poster (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • -ICCOM-CNR, Firenze (Italy). -NIS Centre of Excellence, Torino (Italy). (literal)
Titolo
  • Synthesis, characterization, CO2 uptake and catalytic properties of a chiral Co(II)-MOF containing a thiazolidine-based linker (literal)
Abstract
  • Chiral coordination polymers research has been recently stimulated by the increasing demand for materials for enantioselective catalysis and/or separation. Metal-Organic Frameworks containing optically active ligands have been reported in the literature in the last few years. Here we present the synthesis and characterization of a new Co(II) chiral polymer containing the optically pure (R,R)-thiazolidine-2,4-dicarboxylic acid (H2L): {[Co(L)(H2O)](H2O)}n. The material has been characterized through a plethora of solid-state techniques (single-crystal and powder XRD, EXAFS/XANES, CD, IR, UV-Vis). Applications in the fields of CO2 capture and in heterogeneous alkene oxidation catalysis have been exploited; the results will be presented. (literal)
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