New palladium catalysts on polyketone prepared through different smart methodologies and their use in the hydrogenation of cinnamaldehyde (Articolo in rivista)

Type
Label
  • New palladium catalysts on polyketone prepared through different smart methodologies and their use in the hydrogenation of cinnamaldehyde (Articolo in rivista) (literal)
Anno
  • 2012-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/j.apcata.2012.09.003 (literal)
Alternative label
  • Raspolli Galletti, Anna Maria; Toniolo, Luigi; Antonetti, Claudia; Evangelisti, Claudio; Forte, Claudia (2012)
    New palladium catalysts on polyketone prepared through different smart methodologies and their use in the hydrogenation of cinnamaldehyde
    in Applied catalysis. A, General (Print); Elsevier BV, Amsterdam (Paesi Bassi)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Raspolli Galletti, Anna Maria; Toniolo, Luigi; Antonetti, Claudia; Evangelisti, Claudio; Forte, Claudia (literal)
Pagina inizio
  • 49 (literal)
Pagina fine
  • 59 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://www.sciencedirect.com/science/article/pii/S0926860X12005832 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 447-448 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Department of Chemistry and Industrial Chemistry, University of Pisa Department of Molecular Sciences and Nanosystems, University Ca' Foscari of Venice ICCOM CNR, Via G. Moruzzi 1, Pisa (literal)
Titolo
  • New palladium catalysts on polyketone prepared through different smart methodologies and their use in the hydrogenation of cinnamaldehyde (literal)
Abstract
  • For the first time, polyketone (poly-3-oxotrimethylene, PK) has been employed as support for Pd nanoparticles. Three different approaches have been adopted: (i) reduction of Pd(OAc)2 in EtOH under microwave irradiation, (ii) hydrothermal reduction of the same precursor in EtOH or n-BuOH employing traditional heating and (iii) vaporization of Pd metal through metal vapour synthesis. These supported systems have been characterized by solid state NMR, TEM, ICP, XPS, BET and tested in the selective hydrogenation of cinnamaldehyde (CAL) to hydrocinnamaldehyde (HCAL) as probe reaction. Their catalytic performances have been compared in relation to their preparation procedure and morphology. It is remarkable that these catalysts do not show significant leaching even after several catalytic recycles, thus indicating their high stability and recyclability, ascribed to a stabilizing capacity of this particular polymeric support. (literal)
Editore
Prodotto di
Autore CNR
Insieme di parole chiave

Incoming links:


Prodotto
Autore CNR di
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi
Editore di
Insieme di parole chiave di
data.CNR.it