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[(Me3Si)(2)N](3)Lu: Molecular structure and use as Lu and Si source for atomic layer deposition of Lu silicate films (Articolo in rivista)
- Type
- Label
- [(Me3Si)(2)N](3)Lu: Molecular structure and use as Lu and Si source for atomic layer deposition of Lu silicate films (Articolo in rivista) (literal)
- Anno
- 2007-01-01T00:00:00+01:00 (literal)
- Alternative label
Scarel, G; Wiemer, C; Fanciulli, M; Fedushkin, IL; Fukin, GK; Domrachev, GA; Lebedinskii, Y; Zenkevich, A; Pavia, G (2007)
[(Me3Si)(2)N](3)Lu: Molecular structure and use as Lu and Si source for atomic layer deposition of Lu silicate films
in Zeitschrift für anorganische und allgemeine Chemie (1950)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Scarel, G; Wiemer, C; Fanciulli, M; Fedushkin, IL; Fukin, GK; Domrachev, GA; Lebedinskii, Y; Zenkevich, A; Pavia, G (literal)
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- ISI Web of Science (WOS) (literal)
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- INFM, CNR, MDM Natl Lab, I-20041 Agrate Brianza, MI, Italy; Russian Acad Sci, GA Razuvaev Inst Organomet Chem, Nizhnii Novgorod, Russia; Moscow Phys Engn Inst, Moscow, Russia; STMicroelct, Agrate Brianza, MI, Italy (literal)
- Titolo
- [(Me3Si)(2)N](3)Lu: Molecular structure and use as Lu and Si source for atomic layer deposition of Lu silicate films (literal)
- Abstract
- The molecular structure of tris[bis(trimethylsilyl)amido]-lutetium, [(Me3Si)(2)N](3)Lu, is investigated. An agostic interaction is found between Lu and the Si atom of the silyl group. The performance of [(Me3Si)(2)N](3)Lu as precursor to deposit Lu silicate layers by atomic layer deposition using either H2O or O-3 as oxygen source is studied. Si incorporation in the films is revealed: [(Me3Si)(2)N](3)Lu thermal decomposition and the mentioned agostic interaction contribute both to the phenomenon. [(Me3Si)(2)N](3)Lu thermal de-composition also affects the growth rate of films deposited using H2O. The growth rate of films deposited Using O-3, especially at growth temperatures < 300 degrees C, is extremely high, probably because of the hydrogen atoms existing in [(Me3Si)(2)N](3)Lu. (literal)
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