http://www.cnr.it/ontology/cnr/individuo/prodotto/ID193847
SPECTRAL ANALYSIS IN THE UV-VISIBLE RANGE FOR REVEALING THE MOLECULAR FORM OF COMBUSTION-GENERATED CARBONACEOUS SPECIES (Articolo in rivista)
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- Label
- SPECTRAL ANALYSIS IN THE UV-VISIBLE RANGE FOR REVEALING THE MOLECULAR FORM OF COMBUSTION-GENERATED CARBONACEOUS SPECIES (Articolo in rivista) (literal)
- Anno
- 2012-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1080/00102202.2012.664315 (literal)
- Alternative label
Russo, C.; Stanzione, F.; Alfe, M.; Ciajolo, Anna; Tregrossi, Antonio (2012)
SPECTRAL ANALYSIS IN THE UV-VISIBLE RANGE FOR REVEALING THE MOLECULAR FORM OF COMBUSTION-GENERATED CARBONACEOUS SPECIES
in Combustion science and technology; Gordon and Breach, New York (Stati Uniti d'America)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Russo, C.; Stanzione, F.; Alfe, M.; Ciajolo, Anna; Tregrossi, Antonio (literal)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
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- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- DIC-UNINA, IRC-CNR (literal)
- Titolo
- SPECTRAL ANALYSIS IN THE UV-VISIBLE RANGE FOR REVEALING THE MOLECULAR FORM OF COMBUSTION-GENERATED CARBONACEOUS SPECIES (literal)
- Abstract
- A method of UV-visible spectra analysis was developed for investigating the relationship
between the optical properties and the complex composition/structure of carbonaceous
species formed in a sooting premixed ethylene flame. The UV-visible spectra were measured
on carbonaceous species, caught on quartz plates inserted along the flame and recovered by
solvent treatment. The contribution and the structure of components in a very wide molecular
weight range, from 200 to 1E11 u, were evaluated by size exclusion chromatography coupled
with on-line UV-visible spectroscopy of the dichloromethane-soluble and dry soot fractions.
The optical band gap and the UV peak position of each MW-segregated fraction were evaluated
by means of a spectral deconvolution procedure, to get details on the carbon network
structure in terms of sp2 and sp3 sites and size and stacking of the aromatic units.
The species included in the 1E8-1E11 u range underwent graphitization/growth reactions
during the formation process of carbonaceous species. Large polycyclic aroamtic hydrocarbon
(PAH) molecules and clusters of PAH, included in the 200-1E8 u range, did not
exhibit molecular growth and internal structure transformation, suggesting that they merely
aggregate/coagulate participating to the formation of carbon particles. (literal)
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