The Rh oxide ultrathin film on Rh(100): An x-ray photoelectron diffraction study (Articolo in rivista)

Type
Label
  • The Rh oxide ultrathin film on Rh(100): An x-ray photoelectron diffraction study (Articolo in rivista) (literal)
Anno
  • 2010-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1063/1.3509777 (literal)
Alternative label
  • Rong Rong Zhan, Erik Vesselli, Alessandro Baraldi, Silvano Lizzit, Giovanni Comelli (2010)
    The Rh oxide ultrathin film on Rh(100): An x-ray photoelectron diffraction study
    in THE JOURNAL OF CHEMICAL PHYSICS; American Institute of Physics, Melville [NY] (Stati Uniti d'America)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Rong Rong Zhan, Erik Vesselli, Alessandro Baraldi, Silvano Lizzit, Giovanni Comelli (literal)
Pagina inizio
  • 214701 (literal)
Pagina fine
  • 214707 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://jcp.aip.org/resource/1/jcpsa6/v133/i21/p214701_s1 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 133 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 7 (literal)
Note
  • ISI Web of Science (WOS) (literal)
  • Scopus (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Physics Department and Center of Excellence for Nanostructured Materials, University of Trieste, via A. Valerio 2, 34127--Trieste, Italy IOM CNR, Laboratorio TASC, AREA Science Park, SS 14 km 163.5, 34149 Trieste, Italy Sincrotrone Trieste SCpA, AREA Science Park, SS 14 km 163.5, 34149 Trieste, Italy (literal)
Titolo
  • The Rh oxide ultrathin film on Rh(100): An x-ray photoelectron diffraction study (literal)
Abstract
  • The surface and interface structure of the RhO2 ultrathin film grown on Rh(100) is investigated by means of x-ray photoelectron diffraction. Experimental and simulated one- and two-dimensional angular distribution intensities of the O1s and Rh3d5/2 chemically shifted core levels are quantitatively analyzed. The previously proposed O-Rh-O trilayer model is independently confirmed. A rippled buckling of the metal surface is observed at the oxide-metal interface, with a mean interfacial Rh-O distance which is 0.2 Å larger with respect to previous findings. The link between the local atomic rearrangement and the overall geometric and electronic properties of the oxide is discussed on the basis of a thorough comparison with the corresponding RhO2 rutile structure. (literal)
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