Electrochemical characterization of the surface area of nanoporous gold films (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Electrochemical characterization of the surface area of nanoporous gold films (Articolo in rivista) (literal)

Anno

• 2012-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1149/2.097204jes (literal)

Alternative label

• Rouya E.; Cattarin S.; Reed M.L.; Kelly R.G.; Zangari G. (2012)
  Electrochemical characterization of the surface area of nanoporous gold films
  in Journal of the Electrochemical Society
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Rouya E.; Cattarin S.; Reed M.L.; Kelly R.G.; Zangari G. (literal)

Pagina inizio

• K97 (literal)

Pagina fine

• K102 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://jes.ecsdl.org/content/159/4/K97 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 159 (literal)

Rivista

• Journal of the Electrochemical Society (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 6 (literal)

Note

• ISI Web of Science (WOS) (literal)
• Scopu (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• 1 : Materials Science and Engineering, University of Virginia, Charlottesville, VA 22903, United States 2 : Istituto per l'Energetica e le Interfasi Del C.N.R., Corso Stati Uniti 4, Padova 35127, Italy 4,5 : Materials Science and Engineering, University of Virginia, Charlottesville, VA 22903, United States 3 : Electrical and Computer Engineering Department, University of Virginia, Charlottesville, VA 22903, United States (literal)

Titolo

• Electrochemical characterization of the surface area of nanoporous gold films (literal)

Abstract

• The surface area of nanoporous gold films of thickness up to 930 nm and pores tens of nanometers in size was characterized by various electrochemical methods, including Cu underpotential deposition (UPD), surface Au oxidation/reduction reaction, and electrochemical impedance spectroscopy (EIS). The different approaches provide surface area values that are comparable and, in all cases, linearly increasing with thickness. However, whereas Cu UPD and Au oxidation/reduction methods yielded surface area values in good quantitative agreement, estimates based on EIS measurements were found to be 1.5-1.75 times larger. This discrepancy is tentatively attributed to a higher specific capacitance of nanoporous gold, possibly due both to the presence of residual surface Ag and to the high curvature of the nanoporous structures, that may have different interfacial properties as compared to planar surfaces. (literal)

Prodotto di

• Nanostrutture funzionali su superfici elettrodiche (ET.P06.011.002) (Modulo)
• Institute of Condensed Matter Chemistry and Energy Technologies (ICMATE) (Istituto)

Autore CNR

• SANDRO CATTARIN (Unità di personale interno)

Insieme di parole chiave

• Keywords of "Electrochemical characterization of the surface area of nanoporous gold films" (Insieme di parole chiave)

Incoming links:

Prodotto

• Institute of Condensed Matter Chemistry and Energy Technologies (ICMATE) (Istituto)
• Nanostrutture funzionali su superfici elettrodiche (ET.P06.011.002) (Modulo)

Autore CNR di

• SANDRO CATTARIN (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of the Electrochemical Society (Rivista)

Insieme di parole chiave di

• Keywords of "Electrochemical characterization of the surface area of nanoporous gold films" (Insieme di parole chiave)