http://www.cnr.it/ontology/cnr/individuo/prodotto/ID190179
Assessment of the thermochemistry of oxygen chemisorption and surface oxide desorption during looping combustion of coal char (Articolo in rivista)
- Type
- Label
- Assessment of the thermochemistry of oxygen chemisorption and surface oxide desorption during looping combustion of coal char (Articolo in rivista) (literal)
- Anno
- 2013-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.proci.2012.07.051 (literal)
- Alternative label
Senneca O., Salatino P (2013)
Assessment of the thermochemistry of oxygen chemisorption and surface oxide desorption during looping combustion of coal char
in Proceedings of the Combustion Institute; Elsevier Ltd, Oxford (Regno Unito)
(literal)
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- Senneca O., Salatino P (literal)
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- Istituto di Ricerche sulla Combustione, Consiglio Nazionale delle Ricerche, P.le V. Tecchio 80, 80125 Napoli, Italy
Dipartimento di Ingegneria Chimica, Universita` degli Studi di Napoli Federico II, P.le V. Tecchio 80, 80125 Napoli, Italy (literal)
- Titolo
- Assessment of the thermochemistry of oxygen chemisorption and surface oxide desorption during looping combustion of coal char (literal)
- Abstract
- Carbons have a pronounced tendency to chemisorb oxygen at moderate temperatures and to desorb
surface oxides as combustion products (CO, CO2) once the oxidized fuel is heated up under inert condi-
tions. Based on this feature, a novel process of looping combustion of carbons (CarboLoop) has been
recently proposed, and a proof-of-concept given. The process is based on alternated oxygen chemisorption
on carbon and desorption of surface oxides carried out in dual bed reactors. One of the reactors, operated
with an air feeding, acts as the fuel oxidizer. The second reactor, operated with partly recycled gaseous
effluents (CO2 + impurities), acts as the fuel desorber. Further development of the CarboLoop concept requires the knowledge of the thermochemistry associated with the individual steps of carbon oxidation and of surface oxide desorption, which dictates the energy integration between the reactors. The present
study moves along this path and provides a separate assessment of the thermochemistry of carbon oxida-
tion and desorption stages. The procedure is based on complementary thermoanalytical techniques (TG,
DSC, TPD) as well as on calorimetry. Experimental results obtained with a bituminous coal char indicate
that both oxygen uptake (DHffi?4 kJ/gc) and desorption (DHffi?31 kJ/gc) are exothermic. The strong
exothermicity of the desorption stage, at odds with published data on CO and CO2 abstraction from oxi-
dized carbons, is explained in the light of the cocurrent progress of the stabilization of metastable surface
oxides and of abstraction of CO and CO2 from oxidized carbon. (literal)
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