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Kinetic and Safety Assessment for Salicylic Acid Nitration by Nitric Acid/Acetic Acid System (Articolo in rivista)

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Label

Kinetic and Safety Assessment for Salicylic Acid Nitration by Nitric Acid/Acetic Acid System (Articolo in rivista) (literal)

Anno

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Alternative label

R. Andreozzi, V. Caprio, I. Di Somma, R. Sanchirico (2006)
Kinetic and Safety Assessment for Salicylic Acid Nitration by Nitric Acid/Acetic Acid System
in Journal of hazardous materials (Print)
(literal)

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Dipartimento di Ingegneria Chimica, Facoltà di Ingegneria, Università di Napoli Federico II, P.le V. Tecchio 80, 80125 Napoli, Italia. Istituto di Ricerche sulla Combustione (CNR), P.le V. Tecchio, 80, 80125, Napoli, Italia. (literal)

Titolo

Kinetic and Safety Assessment for Salicylic Acid Nitration by Nitric Acid/Acetic Acid System (literal)

Abstract

The nitration process of salicylic acid for the production of the important intermediate 5-nitrosalicylic acid is studied from thermokinetic and safety points of view. Investigations carried out by considering, as process deviations, the loss of the thermal control point out the possibility of runaway phenomena due to the occurrence of polynitration reactions. Isothermal experiments are carried out in various conditions to assess the involved reaction network and reaction kinetics. (literal)

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