http://www.cnr.it/ontology/cnr/individuo/prodotto/ID188568
Mild hydrolytic cleavage of alpha- ferrocenylalkyl-O-methyl ethers (Articolo in rivista)
- Type
- Label
- Mild hydrolytic cleavage of alpha- ferrocenylalkyl-O-methyl ethers (Articolo in rivista) (literal)
- Anno
- 2012-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.tet.2012.02.074 (literal)
- Alternative label
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Pedotti Sonia; Patti Angela (literal)
- Pagina inizio
- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
- http://www.sciencedirect.com/science/article/pii/S0040402012003006 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Istituto di chimica biomolecolare, Via Paolo Gaifami 18,95126 Catania, Italy (literal)
- Titolo
- Mild hydrolytic cleavage of alpha- ferrocenylalkyl-O-methyl ethers (literal)
- Abstract
- The conversion of alpha-ferrocenylalkyl-O-methyl ethers into the corresponding alcohols was successfully achieved by solvolysis in water/acetone mixtures. The content of water in the solvent markedly influenced the reaction rates. The reactivity of structurally different classes of ferrocenyl ethers was evaluated and in most cases high yields of ferrocenyl alcohols or diols were obtained in a few hours without any additive. Deprotection of less reactive substrates was accelerated in the presence of montmorillonite. The method is simple, environmentally benign and valuable in providing easy access to a variety of ferrocenyl derivatives through the use of the -O-methyl ether protective group. (literal)
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