Microwave spectrum of the axial conformer and potential energy function of the ring puckering motion in fluorocyclobutane (Articolo in rivista)

Type
Label
  • Microwave spectrum of the axial conformer and potential energy function of the ring puckering motion in fluorocyclobutane (Articolo in rivista) (literal)
Anno
  • 1996-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/0022-2860(95)09046-0 (literal)
Alternative label
  • Walther Caminati; Laura B. Favero; Assimo Maris; Paolo G. Favero (1996)
    Microwave spectrum of the axial conformer and potential energy function of the ring puckering motion in fluorocyclobutane
    in Journal of molecular structure (Print); Elsevier Science Publishers, Amsterdam (Paesi Bassi)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Walther Caminati; Laura B. Favero; Assimo Maris; Paolo G. Favero (literal)
Pagina inizio
  • 25 (literal)
Pagina fine
  • 32 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#altreInformazioni
  • prodotto digitalizzato (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 376 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Dipartimento di Chimica \"G. Ciamician\" dell'Universit√†, Via Selmi 2, I-40126 Bologna, Italy; Istituto di Spettroscopia Molecolare del CNR, Via Gobetti 101, I-40129 Bologna, Italy; Dipartimento di Chimica \"G. Ciamician\" dell'Universit√†, Via Selmi 2, I-40126 Bologna, Italy; Dipartimento di Chimica \"G. Ciamician\" dell'Universit√†, Via Selmi 2, I-40126 Bologna, Italy; (literal)
Titolo
  • Microwave spectrum of the axial conformer and potential energy function of the ring puckering motion in fluorocyclobutane (literal)
Abstract
  • The microwave spectrum of fluorocyclobutane has been investigated in the 26-40 GHz frequency range. The spectrum of the axial conformer has been assigned for the first time, while measurements of the equatorial species, and of several of its puckering vibrational satellites, have been extended. The energy of the axial conformer is 620(30) cm(-1) higher than that of the equatorial one. Previously reported potential energy functions of the ring puckering have been corrected, interpreting the available vibrational spacings, the shifts of the rotational constants upon puckering excitation and the centrifugal distortion constants with a flexible model. (literal)
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