http://www.cnr.it/ontology/cnr/individuo/prodotto/ID186007
Ar/HMDSO/O2 Fed Atmospheric Pressure DBDs: Thin Film Deposition and GC-MS Investigation of By-Products (Articolo in rivista)
- Type
- Label
- Ar/HMDSO/O2 Fed Atmospheric Pressure DBDs: Thin Film Deposition and GC-MS Investigation of By-Products (Articolo in rivista) (literal)
- Anno
- 2010-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1002/ppap.200900159 (literal)
- Alternative label
Fiorenza Fanelli, Sara Lovascio, Riccardo d'Agostino,
Farzaneh Arefi-Khonsari, Francesco Fracassi (2010)
Ar/HMDSO/O2 Fed Atmospheric Pressure DBDs: Thin Film Deposition and GC-MS Investigation of By-Products
in Plasma processes and polymers (Print)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Fiorenza Fanelli, Sara Lovascio, Riccardo d'Agostino,
Farzaneh Arefi-Khonsari, Francesco Fracassi (literal)
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- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Dipartimento di Chimica, Università degli Studi di Bari Aldo Moro-IMIP CNR, via Orabona 4, 70126 Bari, Italy
Laboratoire de Génie des Procedés Plasmas et Traitements de Surfaces, EA3492, Université Pierre et Marie Curie ENSCP, 11 rue
Pierre et Marie Curie, Paris 75005, France (literal)
- Titolo
- Ar/HMDSO/O2 Fed Atmospheric Pressure DBDs: Thin Film Deposition and GC-MS Investigation of By-Products (literal)
- Abstract
- The thin film deposition in DBDs fed with Ar/HMDSO/O2 mixtures was studied by comparing
the FT-IR spectra of the deposits with the GC-MS analyses of the exhaust gas. Under the
experimental conditions investigated, oxygen addition does not enhance the activation of the
monomer while it highly influences the chemical composition and structure of the deposited
coating as well as the quali-quantitative distribution of by-products in the exhaust. Without
oxygen addition a coating with high monomer structure
retention is obtained and the exhaust contains
several by-products such as silanes, silanols, and linear
and cyclic siloxanes. The dimethylsiloxane unit seems
to be the most important building block of oligomers.
Oxygen addition to the feed is responsible for an
intense reduction of the organic character of the coating
as well as for a steep decrease, below the quantification
limit, of the concentration of all by-products
except silanols. Some evidences induce to claim that
the silanol groups contained in the deposits are formed
through heterogeneous (plasma-surface) reactions. (literal)
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