Reactivity of trans-[PtCl2(NCMe)2] with cycloaliphatic amines: an ESI and NMR study. X-ray structure of trans[PtCl2{Z-N(H)=C(CH3)NHCHCH2CH2}2 (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Reactivity of trans-[PtCl2(NCMe)2] with cycloaliphatic amines: an ESI and NMR study. X-ray structure of trans[PtCl2{Z-N(H)=C(CH3)NHCHCH2CH2}2 (Articolo in rivista) (literal)

Anno

• 2010-01-01T00:00:00+01:00 (literal)

Alternative label

• Mazzega Sbovata Silvia 1, Michelin Rino A.1 , Mozzon Mirto 1, Venzo Alfonso 2, Bertani Roberta 1, Benetollo Franco 3 (2010)
  Reactivity of trans-[PtCl2(NCMe)2] with cycloaliphatic amines: an ESI and NMR study. X-ray structure of trans[PtCl2{Z-N(H)=C(CH3)NHCHCH2CH2}2
  in Inorganica Chimica Acta (Testo stamp.)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Mazzega Sbovata Silvia 1, Michelin Rino A.1 , Mozzon Mirto 1, Venzo Alfonso 2, Bertani Roberta 1, Benetollo Franco 3 (literal)

Pagina inizio

• 487 (literal)

Pagina fine

• 494 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 363 (literal)

Rivista

• Inorganica Chimica Acta (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• 1 Dipartimento di Processi Chimici dell’Ingegneria, Università di Padova, Padua, Italy 2 C.N.R. Istituto di Scienze e Tecnologie Molecolari, Padua, Italy 3 ICIS – C.N.R., Padua, Italy (literal)

Titolo

• Reactivity of trans-[PtCl2(NCMe)2] with cycloaliphatic amines: an ESI and NMR study. X-ray structure of trans[PtCl2{Z-N(H)=C(CH3)NHCHCH2CH2}2 (literal)

Abstract

• The reactivity of the cyclic primary aliphatic amines cyclopropyl-, cyclopentyl- and cyclohexylamine with cis- and trans-[PtCl2(NCMe)2], under the same experimental conditions, is compared. Whereas cis-[PtCl2(NCMe)2] yields the neutral diamidine compounds, the reactions with trans-[PtCl2(NCMe)2] take place either with addition or substitution processes yielding the neutral diamidine complexes trans-[PtCl2(Amidine)2], the monocationic trans-[PtCl(Amine)(Amidine)2]Cl and the dicationic trans-[Pt(Amine)2(Amidine)2]Cl2 salts. An NMR and ESI study indicate that the main species formed is the monocationic trans-[PtCl(Amine)(Amidine)2]Cl complex. The X-ray structure of trans-[PtCl2{N(H)=C(CH3)NHCHCH2CH2}2] is reported and its supramolecular arrangement is described. (literal)

Prodotto di

• Institute of inorganic chemistry and surfaces (ICIS) (Istituto)

Autore CNR

• FRANCO BENETOLLO (Unità di personale interno)

Insieme di parole chiave

• Keywords of "Reactivity of trans-[PtCl2(NCMe)2] with cycloaliphatic amines: an ESI and NMR study. X-ray structure of trans[PtCl2{Z-N(H)=C(CH3)NHCHCH2CH2}2" (Insieme di parole chiave)

Incoming links:

Prodotto

• Institute of inorganic chemistry and surfaces (ICIS) (Istituto)
• http://www.cnr.it/ontology/cnr/individuo/modulo/ID2435
• http://www.cnr.it/ontology/cnr/individuo/modulo/ID7138

Autore CNR di

• FRANCO BENETOLLO (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Inorganica Chimica Acta (Rivista)

Insieme di parole chiave di

• Keywords of "Reactivity of trans-[PtCl2(NCMe)2] with cycloaliphatic amines: an ESI and NMR study. X-ray structure of trans[PtCl2{Z-N(H)=C(CH3)NHCHCH2CH2}2" (Insieme di parole chiave)