Pyrrolidine dithiocarbamates of Pd(II) (Articolo in rivista)

Type
Label
  • Pyrrolidine dithiocarbamates of Pd(II) (Articolo in rivista) (literal)
Anno
  • 2005-01-01T00:00:00+01:00 (literal)
Alternative label
  • Faraglia G. 1, Sitran S. 2, Montagner D. 1 (2005)
    Pyrrolidine dithiocarbamates of Pd(II)
    in Inorganica Chimica Acta (Testo stamp.)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Faraglia G. 1, Sitran S. 2, Montagner D. 1 (literal)
Pagina inizio
  • 971 (literal)
Pagina fine
  • 980 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 358 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • 1. Dipartimento di Scienze Chimiche, Universita di Padova 2. Istituto di Chimica Inorganica e delle Superfici, C.N.R.,Padova (literal)
Titolo
  • Pyrrolidine dithiocarbamates of Pd(II) (literal)
Abstract
  • The dithioester (CH2)4NCS2CH3 (PyDTM, 1-pyrrolidinecarbodithioate methyl ester) has been prepared by reaction of the parent ammonium salt NH4PyDT (PyDT=(CH2)4NCS2 with methyl iodide in water/ethanol. The reaction of PyDTM with PdCl2 allowed to synthesize either (PdCl2(PyDTM)), in which the ligand is chelated by both sulfur atoms, or(PdCl2(PyDTM)2), in which the ligand acts as monodentate through the thiocarbonyl sulfur. Thermal degradation of(PdCl2(PyDTM)), yielded the (PdCl2(PyDTM))n species as an intermediate, which, in the presence of donors as chloride ions or dimethyl sulfoxide (DMSO), gave the complexes [PdCl(PyDT)(DMSO)] and NR4(PdCl2(PyDT)). Moreover, PyDTM was found to react with various [PdCl(dithiocarbamato)]n intermediates to form the mixed species [PdCl(dithiocarbamato)(PyDTM)], whose thermal degradation yielded the [Pd(dithiocarbamato)(PyDT)] complexes. The behaviour of the prepared compounds in either solution or solid phase has been described on the basis of IR and proton NMR spectra and thermogravimetric analysis (TG and DTA). (literal)
Prodotto di
Autore CNR
Insieme di parole chiave

Incoming links:


Prodotto
Autore CNR di
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi
Insieme di parole chiave di
data.CNR.it