Effect of the Mg/Al ratio of the hydrotalcite-type precursor on the dispersion and activity of Rh and Ru catalysts for the partial oxidation of methane (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Effect of the Mg/Al ratio of the hydrotalcite-type precursor on the dispersion and activity of Rh and Ru catalysts for the partial oxidation of methane (Articolo in rivista) (literal)

Anno

• 2004-01-01T00:00:00+01:00 (literal)

Alternative label

• Francesco Basile, Giuseppe Fornasari, Valerio Rosetti, Ferruccio Trifirò, Angelo Vaccari (2004)
  Effect of the Mg/Al ratio of the hydrotalcite-type precursor on the dispersion and activity of Rh and Ru catalysts for the partial oxidation of methane
  in Catalysis Today; Academic Press Elsevier, Amsterdam (Paesi Bassi)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Francesco Basile, Giuseppe Fornasari, Valerio Rosetti, Ferruccio Trifirò, Angelo Vaccari (literal)

Pagina inizio

• 293 (literal)

Pagina fine

• 297 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 91-92 (literal)

Rivista

• Catalysis Today (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 5 (literal)

Note

• Scopus (literal)
• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Dip. di Chimica Industriale e dei Materiali, Università di Bologna, Viale Risorgimento 4, 40136 Bologna (BO), Italy (literal)

Titolo

• Effect of the Mg/Al ratio of the hydrotalcite-type precursor on the dispersion and activity of Rh and Ru catalysts for the partial oxidation of methane (literal)

Abstract

• Active and stable catalysts for the partial oxidation of methane based on Rh and Ru nanoparticles strongly interacting with a MgO or spinel matrix have been prepared by calcination and reduction of hydrotalcite-type precursors. A Rh catalyst containing an high metal loading was used to calculate, by Rietveld analysis, the distribution of the Rh in the MgO-type and spinel-type phases obtained after calcination. The Rh particle size distribution analysed after reduction by HRTEM, has evidenced that the size of Rh particles supported on MgO is smaller than that of Rh particles supported on spinel matrix. The differences in the catalytic activity of the two type of matrix have been studied changing the Mg/Al ratio of the precursor. High Mg/Al ratio depressed the formation of the spinel and led to a narrow distribution of the particle size. The sample with the highest percentage of the MgO phase showed the highest activity. Similar tests have been carried out with Ru containing samples and in this case the increase of the MgO phase decreases the formation of RuO2. (literal)

Editore

• Academic Press Elsevier (Editore)

Prodotto di

• Institute of science and technology for ceramics (ISTEC) (Istituto)

Autore CNR

• ANGELO VACCARI (Unità di personale esterno)

Insieme di parole chiave

• Parole chiave di "Effect of the Mg/Al ratio of the hydrotalcite-type precursor on the dispersion and activity of Rh and Ru catalysts for the partial oxidation of methane" (Insieme di parole chiave)

Incoming links:

Prodotto

• Institute of science and technology for ceramics (ISTEC) (Istituto)

Autore CNR di

• ANGELO VACCARI (Unità di personale esterno)

Editore di

• Academic Press Elsevier (Editore)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Catalysis Today (Rivista)

Insieme di parole chiave di

• Parole chiave di "Effect of the Mg/Al ratio of the hydrotalcite-type precursor on the dispersion and activity of Rh and Ru catalysts for the partial oxidation of methane" (Insieme di parole chiave)