http://www.cnr.it/ontology/cnr/individuo/prodotto/ID183805
Distillation law and exponential model of isotope fractionation (Articolo in rivista)
- Type
- Label
- Distillation law and exponential model of isotope fractionation (Articolo in rivista) (literal)
- Anno
- 2012-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.ijms.2011.09.008 (literal)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Pagina inizio
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#altreInformazioni
- http://www.newsrx.com/newsletters/Science-Letter/2012-02-24/3802242012603SL.html
http://www.sciencedirect.com/science/article/pii/S1387380611004088
http://ac.els-cdn.com/S1387380611004088/1-s2.0-S1387380611004088-main.pdf?_tid=bfb13adb0060c95193c70eccead14144&acdnat=1335877407_24c57790663e5d48b8386fcb4b06708d (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
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- Titolo
- Distillation law and exponential model of isotope fractionation (literal)
- Abstract
- The exponential law is an empirical model which is used to describe the isotopic fractionation both in
instrumental (thermal ionization- and induced coupled plasma-source mass spectrometry) and in natural
processes. It is shown that isotopic fractionation which occurs according to this law can be interpreted
in terms of a Rayleigh-type distillation process, in which the value of the vapour/residue distribution
coefficient for the various isotopes of an element is a natural logarithmic function of the isotope mass:
D = D0 + a ln(m(m0)? .
?In this equation, D0 is the value of the vapour/residue distribution coefficient for a reference mass m0
and
a = p/(1+ln f ) ,
where p is the instantaneous value of the so called \"fractionation exponent\" (or \"fractionation coefficient\")
of the exponential law, and f is the residual mass fraction of the sample at the same instant. (literal)
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