http://www.cnr.it/ontology/cnr/individuo/prodotto/ID183773
Water Oxidation at a Tetraruthenate Core Stabilized by Polyoxometalate Ligands: Experimental and Computational Evidence To Trace the Competent Intermediates (Articolo in rivista)
- Type
- Label
- Water Oxidation at a Tetraruthenate Core Stabilized by Polyoxometalate Ligands: Experimental and Computational Evidence To Trace the Competent Intermediates (Articolo in rivista) (literal)
- Anno
- 2009-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1021/ja905067u (literal)
- Alternative label
Andrea Sartorel, Pere Miro, Enrico Salvadori, Sophie Romain, Mauro Carraro,
Gianfranco Scorrano, Marilena Di Valentin, Antoni Llobet, Carles Bo, Marcella Bonchio (2009)
Water Oxidation at a Tetraruthenate Core Stabilized by Polyoxometalate Ligands: Experimental and Computational Evidence To Trace the Competent Intermediates
in Journal of the American Chemical Society (Print); ACS, American chemical society, Washington, DC (Stati Uniti d'America)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Andrea Sartorel, Pere Miro, Enrico Salvadori, Sophie Romain, Mauro Carraro,
Gianfranco Scorrano, Marilena Di Valentin, Antoni Llobet, Carles Bo, Marcella Bonchio (literal)
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- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- 1. Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain
2. Univ Padua, ITM CNR, I-35131 Padua, Italy
3. Univ Rovira & Virgili, Tarragona, Spain (literal)
- Titolo
- Water Oxidation at a Tetraruthenate Core Stabilized by Polyoxometalate Ligands: Experimental and Computational Evidence To Trace the Competent Intermediates (literal)
- Abstract
- Converging UV-vis, EPR, rRaman, and DFT calculations highlight the evolution of [Ru(4)(H(2)O)(4)(mu-O)(4)(mu-OH)(2)(gamma-SiW(10)O(36))(2)](10-), 1, to high-valent intermediates. In analogy with the natural enzyme, five different oxidation states, generated from 1, have been found to power the catalytic cycle for water oxidation. A high electrophilic tetra ruthenium (V)-hydroxo species is envisaged as the competent intermediate, undergoing nucleophilic attack by an external water molecule as a key step in the formation of a new O-O bond under catalytic conditions (literal)
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