The ligating ability of functionalised diaminodimethylsilanes towards zirconium(IV) (Articolo in rivista)

Type
Label
  • The ligating ability of functionalised diaminodimethylsilanes towards zirconium(IV) (Articolo in rivista) (literal)
Anno
  • 2004-01-01T00:00:00+01:00 (literal)
Alternative label
  • V. Passarelli, F. Benetollo, P. Zanella (2004)
    The ligating ability of functionalised diaminodimethylsilanes towards zirconium(IV)
    in European journal of inorganic chemistry (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • V. Passarelli, F. Benetollo, P. Zanella (literal)
Pagina inizio
  • 1714 (literal)
Pagina fine
  • 1723 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Titolo
  • The ligating ability of functionalised diaminodimethylsilanes towards zirconium(IV) (literal)
Abstract
  • The functionalised diaminodimethylsilanes SiMe2[NH-(CH2)nX]2 (X = NMe2, n = 2, H2L1; n = 3, H2L2; X = OMe, n = 2, H2L3; n = 3, H2L4) have been synthesised by aminolysis ofSiMe2Cl2 with NH2(CH2)nX, and their ligating ability towards zirconium(iv) has been investigated. The syntheses of [ZrY2(L)] (Y = Cl, NMe2, Me; L = L1, L2, L3, L4) are reported and the solid-state structures of some selected compounds determined by X-ray crystallography. In addition, the solution molecular structures of all the metal derivatives have been elucidated by variable-temperature multinuclear 1D/2D NMR spectroscopy, and the dynamics have been investigated in some selected cases. (literal)
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